Synthesis, structural, and DFT studies of Cu(II) dithiocarbamate complexes

Antiproliferative activity of Fe(ii), Co(ii), Ni(ii), Cu(ii), and Zn(ii) complexes of dithiocarbamate: synthesis, structural characterization, and thermal studies

“…These bond distances and angles are in agreement with other reported copper( ii ) dithiocarbamato complexes. 43,44 The N–C bond lengths of NCS 2 moieties of the ligand N(1)–C(1) = 1.327(2) are slightly shorter than the N–C single bond length signifying the partial double bond character and suggesting the delocalization of the charge in the NCS 2 moiety. 45,46 In the solid state, complex 4 is stabilized by weak intermolecular C–H⋯O hydrogen bonding interactions occurring between the C–H hydrogen of the cyclohexyl ring and the oxygen atoms of the methoxy group leading to a wave-like architecture (Fig.…”

“…These bond distances and angles are in agreement with other reported copper(II) dithiocarbamato complexes. 43,44 The N-C bond lengths of NCS 2 moieties of the ligand N(1)-C(1) = 1.327(2) are slightly shorter than the N-C single bond length signifying the partial double bond character and suggesting the delocalization of the charge in the NCS 2 moiety. 45,46 In the solid state, complex 4 is stabilized by weak…”