Synthesis, spectroscopic characterization, and SC-XRD study of one privileged heteronuclear Ni(II)/Hg(II)-Salen complex: An exclusive DFT outlook

Experimental and theoretical study of novel amino‐functionalized P(V) coordination compounds suggested as inhibitor of MProof SARS‐COV‐2 by molecular docking study

“…These such complexes have been recently received attention due to their catalytic, magnetic, electric, luminescence and fluorescence properties and also, for their biomedical applications such as anticancer, antibacterial, antimicrobial and antiviral. [62][63][64][65][66] In the first comparison, the AIM and NBO analyses results are considered. The charge density analysis for 1-3 shows the values of ρ(r) (around +0.073 a.u.)…”

“…These such complexes have been recently received attention due to their catalytic, magnetic, electric, luminescence and fluorescence properties and also, for their biomedical applications such as anticancer, antibacterial, antimicrobial and antiviral. [ 62–66 ]…”

“…Form HS analysis, the H … H and H … C/C … H contacts and then, H … O/O … H and H … N/N … H (for 1 and 2 ) or H … Cl/Cl … H and H … N/N … H (for 3 ) are contacts with the most contribution related to the total HS. As it is seen, the H … O/O … H contact dominate the H … N/N … H for the metal‐phosphramide complexes 1 and 2 , whereas in the Salen complexes, [ 63,69 ] the H … N/N … H is maximum than the H … O/O … H. This can be attributed to the uncoordinated phosphoryl oxygen atoms in 1 and 2 which are involved in the N―H … O hydrogen bonding, where in the phosphoramide complexes with the coordinated phosphoryl oxygen atoms, [ 25 ] similarly the H … N/N … H input is larger than the H … O/O … H.…”

Hydrogels Loaded with Atorvastatin‐Metal Organic Framework Have a Preventive Effect on Coronary Heart Disease

“…[16][17][18][19][20][21] Within the large number of organic ligands, N-heterocyclic carboxylate ligands have drawn much interest from chemists and biologists for its rich coordination pattern and function characteristics, and as hydrogen bond donors and acceptors for solution environments. [22][23][24][25] The recent literature, however, indicates that Ca(II)-based coordination polymers display intriguing biological activities. As an example, Mishra and his colleagues prepared a novel heterobimetallic Zn(II)/Ca(II) complex using a potential hexavalent N 2 O 4 proligand that showed improved antimicrobial activity over the ligand against all tested microorganisms.…”

Synthesis and crystal structures of two tri- and tetra-heterometallic Ni(ii)–Mn(ii)/Ni(ii)–Co(iii) complexes from two different Ni(ii)-containing metalloligands: effective catalytic oxidase activity and Schottky device approach

“…[1][2][3][4][5][6] In the past, numerous heterometallic complexes have been created by directly mixing a metal centre with an N 2 O 2 donor Schiff base ligand. [7][8][9] These Schiff bases are widely used in coordination chemistry research due to their simple synthesis procedures, one-pot condensation of a diamine with substituted salicylaldehyde derivatives, and their exceptional complexing power. The creation of a metalloligand by utilizing an N 2 O 2 donor Schiff base ligand and a metal salt has recently emerged as a common method for creating heterometallic complexes.…”