Synthesis, optimized geometry, optical, electronic, electrical, stability and Z scan analysis of tetra-aqua-bis (p-toluene Sulphonate)-Calcium (PTC) single crystal

Beena, J.; Jebamalar, A. S.; Sindhusha, S.; Kamalesh, T.

doi:10.1016/j.optmat.2022.112938

Cited by 6 publications

(3 citation statements)

References 38 publications

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“…It is evident from the graph that as photon energy (hν) increases, the refractive index falls. [ 23 ] This decrease in refractive index highlights the consistent dispersion behavior that the 2ADPTS crystal exhibits. The calculated linear refractive index ( n x ) for the 2ADPTS crystal at 532 nm was 1.84.…”

Section: Resultsmentioning

confidence: 69%

Growth, Optical, Thermal, Antibacterial Activity and Computational Study of Highly Efficient Organic NLO Crystal: 2‐Amino‐1‐methyl‐4‐oxo‐4, 5‐dihydro‐1H‐imidazol‐3‐ium 4‐methyl‐benzene‐sulfonate

Shyla,

Jebamalar,

Vinitha

2023

Cryst. Res. Technol.

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A good organic single crystal of 2‐Amino‐1‐methyl‐4‐oxo‐4, 5‐di‐hydro‐1H‐imidazol‐3‐ium 4‐methyl‐benzene‐sulfonate (2ADPTS) is grown by slow evaporation technique, and the orthorhombic system with noncentrosymmetric space group (P212121) is corroborated by single‐crystal X‐ray diffraction analysis. The structural parameters of the 2ADPTS crystal are investigated and weighted up with the theoretical interpretation. The Hydrogen–Hydrogen interaction with (43.6%) in 2ADPTS promotes crystal structure packing stabilization. The presence of various functional groups and chemical composition of the 2ADPTS compound is identified by FTIR and FT‐Raman spectroscopy. The natural bond orbital evaluation interprets all the possible hydrogen bonding interactions and charge delocalizations in the crystal structure. Thermal analysis confirmed the thermal stability of the 2ADPTS crystal. The absorption spectrum of the 2ADPTS crystal is recorded using UV–Vis spectroscopy. The third‐order nonlinear property of the 2ADPTS crystal is confirmed by using the Z‐scan technique. The higher significant antibacterial activity of 2ADPTS is carried out by the standard Kirby‐Bauer test against four pathogenic bacteria commonly called the agar well diffusion process.

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Section: Resultsmentioning

confidence: 69%

Growth, Optical, Thermal, Antibacterial Activity and Computational Study of Highly Efficient Organic NLO Crystal: 2‐Amino‐1‐methyl‐4‐oxo‐4, 5‐dihydro‐1H‐imidazol‐3‐ium 4‐methyl‐benzene‐sulfonate

Shyla,

Jebamalar,

Vinitha

2023

Cryst. Res. Technol.

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“…The quantity of light lost due to scattering and absorption per unit distance of the penetrating medium that is, the minimal amount of energy lost during electromagnetic wave passage through the material is quantified by the extinction coefficient ( K ). 30…”

Section: Resultsmentioning

confidence: 99%

Investigation on the growth aspects and properties of rubidium hydrogen succinate hydrate single crystal for NLO applications

Kavitha,

Vizhi

2024

RSC Adv.

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“…Consequently, the hyperpolarizability value is high, making this styryl bridge one of the most prominent delocalized conjugated structures. [81] This CT induces more dipole VMST [76] LiNbO 3 [77] KDP [78] Dye doped PMMA [79] χ (3) value (esu) 4.30937×10 À 10 9.696×10 À 12 33.7×10 À 14 2.04×10 À 14 0.72×10 À 13 oscillations within the material; as a result, there is a polarisation surge which in turn boosts the NLO activity in the DSNA crystal. The interlinkage anion (SO 3 ligand) and cation also contributes to the titular crystal's NLO origin.…”

Section: Open Aperture Modementioning

confidence: 99%

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

Anand

Rani

2023

ChemPhotoChem

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The idea of incorporating a novel counter anion group with the organic stilbazolium cation (C16H19N2+) yields a new third harmonic generation active single crystal of 4‐[2‐(4‐Dimethylamino‐phenyl)‐vinyl]‐1‐methyl‐pyridinium 2‐Nitroaniline‐4‐sulfonate (DSNA). The slow evaporation solution growth technique is employed to obtain DSNA crystals, whose nonlinear responses are analyzed through a continuous wave laser Z scan experiment. The thermally induced strong reverse saturation absorption and self‐defocusing behaviour of DSNA crystal infers the aptness of the material as an optical limiting device. Optical characterization outcomes imply that the lower absorption edge falls in the visible region (530 nm), with a broad transparency range of 0.53 to 1 μm. Exploration of other optical constants, extinction coefficient (k = 10‐4), emission wavelength (620 nm – red light), optical (σopt = 1010 Ωm‐1) and electrical conductivity (σelc = 1011 Ωm‐1) also concludes that DSNA crystal is a possible applicant for optoelectronic devices. The various bonds and corresponding lengths and angles involved in the formation of DSNA ionic crystal are evaluated by means of the Single Crystal X‐Ray Diffraction (SCXRD) technique. Linear and nonlinear optical property findings undoubtedly affirm that the titular DSNA crystal is an effectual Nonlinear Optical (NLO) crystal.

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Synthesis, optimized geometry, optical, electronic, electrical, stability and Z scan analysis of tetra-aqua-bis (p-toluene Sulphonate)-Calcium (PTC) single crystal

Cited by 6 publications

References 38 publications

Growth, Optical, Thermal, Antibacterial Activity and Computational Study of Highly Efficient Organic NLO Crystal: 2‐Amino‐1‐methyl‐4‐oxo‐4, 5‐dihydro‐1H‐imidazol‐3‐ium 4‐methyl‐benzene‐sulfonate

Growth, Optical, Thermal, Antibacterial Activity and Computational Study of Highly Efficient Organic NLO Crystal: 2‐Amino‐1‐methyl‐4‐oxo‐4, 5‐dihydro‐1H‐imidazol‐3‐ium 4‐methyl‐benzene‐sulfonate

Investigation on the growth aspects and properties of rubidium hydrogen succinate hydrate single crystal for NLO applications

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

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