Synthesis of water-soluble ionic terpolymers by inverse microemulsion and solution polymerization methods

Abstract

Terpolymers based on acrylamide, N-vinylpyrrolidone and (vinylbenzyl)trimethylammonium chloride (VBTA) were synthesized using inverse microemulsion and solution methods. The microemulsion promoted the incorporation of VBTA in the terpolymer structure.

Inhibition Mechanism of Some Vinylalkylimidazolium-Based Polymeric Ionic Liquids against Acid Corrosion of API 5L X60 Steel: Electrochemical and Surface Studies

“…99,100 Poly[VIMC4][Im] was synthesized through a previously reported procedure, 27 using 0.02 mol % of BAM per mole of monomer in the initial reaction mixture (see Figure 14). 101,102 at this stage, the decomposition of repeating PIL units is also found. 103,104 The second stage was related to the decomposition of the repeating units of n-vinylpyrrolidone.…”

“…In contrast, the decomposition of the terpolymers poly[VIM4C][Br] and poly[VIM2C][Br] took place in two clearly defined stages at 245 and 250 °C, respectively. The first stage was ascribed to the decomposition of side acrylamide groups by the elimination of ammonia, forming imide groups; 101 , 102 at this stage, the decomposition of repeating PIL units is also found. 103 , 104 The second stage was related to the decomposition of the repeating units of n -vinylpyrrolidone.…”

Construction, molecular docking simulation and evaluation of electrochemical properties of polymeric nanospheres comprising novel synthesized monomer via green microemulsion polymerization

“…An enormous number of functional monomers can be polymerized through the so‐called microemulsion polymerization process to create several multifunctional co‐ or terpolymer nanospheres 30 . Such a simple microemulsion copolymerization as methyl methacrylate (MMA) with any other monomer that includes different functional groups as amino groups into polymeric systems such as dimethyl amino ethyl methacrylate (DMAEMA) 31,32 .…”

“…An enormous number of functional monomers can be polymerized through the so-called microemulsion polymerization process to create several multifunctional co-or terpolymer nanospheres. 30 Such a simple microemulsion copolymerization as methyl methacrylate (MMA) with any other monomer that includes different functional groups as amino groups into polymeric systems such as dimethyl amino ethyl methacrylate (DMAEMA). 31,32 Where the poly (DMAEMA) has the amino groups' capacity, which improves the binding ability with a variety of materials, and can be used to cap metal, 33 semiconductor, [34][35][36] and magnetic sustainability.…”