Synthesis of nitric acid esters from alcohols in a dinitrogen pentoxide/carbon dioxide liquid system

Kuchurov, Ilya V.; Fomenkov, Igor V.; Zlotin, Sergei G.; Tartakovsky, Vladimir A.

doi:10.1016/j.mencom.2012.03.004

Cited by 12 publications

(15 citation statements)

References 30 publications

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“…[161] The protocolp roved to be applicable to green nitrationo fv ariousa lcohols and polyols. It is based on the inverse reagent mixingo rder (dosing of N 2 O 5 solution in liquid CO 2 to as olution or suspension of an alcohol in the same media;S cheme 33).…”

Section: O-nitrationreactionsmentioning

confidence: 99%

“…It is based on the inverse reagent mixingo rder (dosing of N 2 O 5 solution in liquid CO 2 to as olution or suspension of an alcohol in the same media;S cheme 33). [161] The protocolp roved to be applicable to green nitrationo fv ariousa lcohols and polyols. In the presence of just 10 mol %e xcess of N 2 O 5 ,t he corresponding nitroesters 1-5 bearingu pt os ix nitrate groups were obtained in one step with excellent yields.…”

Section: O-nitrationreactionsmentioning

confidence: 99%

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Prospective Symbiosis of Green Chemistry and Energetic Materials

et al. 2017

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A global increase in environmental pollution demands the development of new "cleaner" chemical processes. Among urgent improvements, the replacement of traditional hydrocarbon-derived toxic organic solvents with neoteric solvents less harmful for the environment is one of the most vital issues. As a result of the favorable combination of their unique properties, ionic liquids (ILs), dense gases, and supercritical fluids (SCFs) have gained considerable attention as suitable green chemistry media for the preparation and modification of important chemical compounds and materials. In particular, they have a significant potential in a specific and very important area of research associated with the manufacture and processing of high-energy materials (HEMs). These large-scale manufacturing processes, in which hazardous chemicals and extreme conditions are used, produce a huge amount of hard-to-dispose-of waste. Furthermore, they are risky to staff, and any improvements that would reduce the fire and explosion risks of the corresponding processes are highly desirable. In this Review, useful applications of almost nonflammable ILs, dense gases, and SCFs (first of all, CO ) for nitration and other reactions used for manufacturing HEMs are considered. Recent advances in the field of energetic (oxygen-balanced and hypergolic) ILs are summarized. Significant attention is paid to the SCF-based micronization techniques, which improve the energetic performance of HEMs through an efficient control of the morphology and particle size distribution of the HEM fine particles, and to useful applications of SCFs in HEM processing that makes them less hazardous.

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Section: O-nitrationreactionsmentioning

confidence: 99%

Section: O-nitrationreactionsmentioning

confidence: 99%

Prospective Symbiosis of Green Chemistry and Energetic Materials

et al. 2017

Self Cite

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“…The cell body and the lid (4) are made of steel 316 SS and Hastelloy C22, respectively. The body of the cell is protected from the reaction mixture by PTFE covering (6). The plane parallel capacitor of two electrodes (5) of platinized titanium is placed inside the cell.…”

Section: Methodsmentioning

confidence: 99%

“…General Procedure for the Dielectric Constant Measurement of the Nitrating Agent Solution in L CO 2 The capacitance of empty cell (4) C 0 was deter mined using laboratory multimeter Hewlett Packard 4262A (5); the cell was kept in a thermostat (6) for 30 min at 20°C (Fig. 2).…”

Section: Methodsmentioning

confidence: 99%

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Relative permittivity of monocomponent and binary solutions of N2O5 in liquid CO2 and their activity in nitration of cellulose

Guskov

Kuchurov

Zlotin

2015

Russ. J. Phys. Chem. B

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Static relative permittivity of liquid carbon dioxide solutions of dinitrogen pentoxide and its mix tures with nitric, acetic or trifluoroacetic acids is measured. The procedure for nitration of cellulose acquired from various natural noncotton sources (wood, linen, hemp) by mixtures of dinitrogen pentoxide and 100% nitric acid in a carbon dioxide medium is developed. A supercritical drying technique is implemented for dehydration of wet nitrocellulose.

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From heart drug to propellant fuels: Designing nitroglycerin-ionic liquid composite as green high-energy hypergolic fluids

Wang

Jin

et al. 2021

Combustion and Flame

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Synthesis of nitric acid esters from alcohols in a dinitrogen pentoxide/carbon dioxide liquid system

Cited by 12 publications

References 30 publications

Prospective Symbiosis of Green Chemistry and Energetic Materials

Prospective Symbiosis of Green Chemistry and Energetic Materials

Relative permittivity of monocomponent and binary solutions of N2O5 in liquid CO2 and their activity in nitration of cellulose

From heart drug to propellant fuels: Designing nitroglycerin-ionic liquid composite as green high-energy hypergolic fluids

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