Synthesis of New Palladium(II) Complexes Containing Hemilabile N‐(Alkylamino)pyrazole Ligands: Spectroscopic Analysis and Crystal Structure of [PdCl(ddae)]Cl·H₂O {ddae = Bis[2‐(3,5‐dimethyl‐1‐pyrazolyl)ethyl]ethylamine}

Abstract

Treatment of the tridentate (NNЈN) N-alkylaminopyrazole

Aminopyrazole-Based Ligand Induces Gold Nanoparticle Formation and Remains Available for Heavy Metal Ions Sensing. A Simple “Mix and Detect” Approach

“…The coordination chemistry of pyrazole-derived amino ligands has been extensively studied by our group . Leaning on the bases of the behavior of these type of ligands in coordination chemistry, our objective in this work is to gain an insight into the nanosize scale mechanism of gold ion interaction with N -alkylaminopyrazole (−NHR, −NR 2 ) ligands (1-[2-(ethylamino)ethyl]-3,5-diphenylpyrazole ( L1 ), 1-[2-(diethylamino)ethyl]-3,5-diphenylpyrazole ( L2 ), 1-[2-(octylamino)ethyl]-3,5-diphenylpyrazole ( L3 ), and 1-[2-(dioctylamino)ethyl]-3,5-diphenylpyrazole ( L4 ), Figure a) , to form AuNPs.…”

A supramolecular recyclable catalyst for aqueous Suzuki–Miyaura coupling

“…PdCl 2 (NCCH 3 ) 2 (0.070 g, 0.27 mmol) in dry CH 2 Cl 2 (10 mL) and Ad-L (0.103 g, 0.27 mmol) in dry CH 2 Cl 2 (5 mL) were mixed and stirred at room temperature for 12 h (ref 62…”

Copper complexes from 3,5-disubstituted N-hydroxyethylpyrazole ligands: Cleavage of C N bond as well as formation of second coordination sphere complexes

“…In the past two decades our efforts have been focused in 1-, 3-and 5-trisubstituted ligands, and, particularly, in incorporating new functional groups in position 1-. For instance, pyrazole ligands bearing groups such as amines [16,17], thioethers [18], sulfoxides/sulfones [19], phosphines [20], phosphinites [21] and alcohols [22] have been obtained, and their coordination behaviour against different metal salts studied. In this sense, we have recently reported the coordination behaviour of one N,O-hybrid pyrazole ligand (2-(3,5-dimethyl-1H-pyrazol-1-yl) ethanol against different Cu(II) salts [23].…”