Synthesis of N-Benzylideneaniline by Schiff base reaction using Kinnow peel powder as Green catalyst and comparative study of derivatives through ANOVA techniques

Abstract

The cheap and easy availability of the Kinnow peel waste has reported various applications due to presence of multifunctional groups. Therefore, in present study we explored its application to synthesize N-Benzylideneaniline and its derivatives based on Schiff base reaction. Kinnow peel powder is characterized by FTIR, TEM, SEM, XRD, EDX, and TGA for functional groups, morphology, surface, elements and thermal stability. Benzaldehyde, aniline, and their derivatives such as 4-methyl benzaldehyde, 4-hydroxy benzaldehyde, 4-methoxy benzaldehyde, and 4-methoxy aniline have been used to compare the efficacy of the Schiff base reaction using analysis of variance (ANOVA) and it has been observed that combination of Aniline and benzaldehyde for Schiff base reaction provided 85% yield of relative product.

Stimuli-Responsive Polymer-Based Nanosystems for Cancer Theranostics

“…131 Amine, Schiff base, and aconitic acid were common pH-responsive functional groups and have been reported in a number of works to prepare transformable nanosystems (Table 2). 132,133 Depending on the pH, amines can be protonated at acidic pH and become positively charged. This process is reversible with relatively fast kinetics.…”

Breaking the Equilibrium and Improving the Yield of Schiff Base Reactions by Pervaporation: Application to a Reaction Involving n-butylamine and Benzaldehyde

“…The pervaporation cell has a capacity of 120 mL. In static mode, the temperature of the load is kept constant during the process thanks to the circulation of a thermostatic fluid (water) passing between the walls of the cell containing the load (1). The pervaporation process operates in static mode and the temperature of the feed in the tank (2) is kept constant using a thermostatic coil immersed in the mixture.…”

“…This theory states that M c values increased with the swelling ratio of the hydrogel. According to this approach, the molecular weight between adjacent crosslinks is calculated using Equation (1) [44]…”

“…The structure of n-butyl-1-phenylmethanimine was characterized by FTIR, 1 HNMR, and DSC analyses. The crosslinking of PVA was demonstrated by a water solubility test (θ-solvent) at 90 • C (the temperature at which the corresponding non-crosslinked PVA dissolves, called the θ temperature).…”

“…Researchers are currently facing new challenges in reducing chemical waste, reaction times, economically efficient chemicals, and harmful chemicals in organic transformations. Green chemistry plays the most important role in synthetic chemistry, maximizing the yield of reaction products while limiting side products by using less hazardous chemicals [1].…”