2005
DOI: 10.1016/j.tet.2005.06.006
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis of functionalized polyhedral oligomeric silsesquioxane (POSS) macromers by microwave assisted 1,3-dipolar cycloaddition

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

0
19
0

Year Published

2005
2005
2020
2020

Publication Types

Select...
5
4

Relationship

0
9

Authors

Journals

citations
Cited by 33 publications
(19 citation statements)
references
References 46 publications
0
19
0
Order By: Relevance
“…This is a level of theory used by other researchers [51] to calculate properties for similar structures. We first performed unconstrained geometry optimization on an isolated spherosilicate cube with a eOTiCl 3 group attached into it and an isolated H 2 molecule, Then the optimized H 2 was placed near the eOTiCl 3 group and the geometry of the combined structure was optimized.…”
Section: Quantum Mechanical Calculationsmentioning
confidence: 99%
“…This is a level of theory used by other researchers [51] to calculate properties for similar structures. We first performed unconstrained geometry optimization on an isolated spherosilicate cube with a eOTiCl 3 group attached into it and an isolated H 2 molecule, Then the optimized H 2 was placed near the eOTiCl 3 group and the geometry of the combined structure was optimized.…”
Section: Quantum Mechanical Calculationsmentioning
confidence: 99%
“…In recent years, strongly segregating BCPs such as silicon‐containing BCPs have been highly promising for such applications . In particular, POSS‐containing BCPs have a T g highly suitable for forming thin films and a naturally increased etching contrast to oxygen plasma treatment, making it highly suitable for fabricating well‐defined nanopatterns . By tuning the BCP to self‐assemble into hexagonally packed cylindrical structures of the POSS‐containing domain with a parallel orientation relative to the substrate, periodic L/S structures can be obtained after selectively etching the organic major domain.…”
Section: Introductionmentioning
confidence: 99%
“…This is especially true of 1,3-dipolar cycloadditions (cf., Chapter 17) [93]. Because these reactions are well known to react via asynchronous mechanisms, MW-specific effects are expected, and very often apparent when MW and were closely checked under similar sets of conditions [94,95]. A specific lit.…”
Section: Isopolar Transition-state Reactionsmentioning
confidence: 99%