Synthesis of Fluorinated Octahydro-2H-Chromenes in the Presence of the BF3·Et2O–H2O Catalytic System

Ильина, И. В.; Patrusheva, Oksana S.; Корчагина, Д. В.; Волчо, К. П.; Salakhutdinov, N. F.

doi:10.1007/s10593-020-02743-z

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R E C O R D R E V I E W T H E C H E M I C a L R E C O R D1

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2024

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“…[67] Subsequently, the research group of Salakhutdinov synthesised fluoro-and hydroxy-containing octahydro-2H-chromenes by the Prins reaction starting from (À )-isopulegol 2 with carbonyl compounds of various types (aromatic, aliphatic, heteroaromatic aldehydes and aliphatic ketones) in the presence of the BF 3 • Et 2 O/H 2 O system in 2020 (Scheme 7). [68,69] The activity of the produced compounds against the influenza A/Puerto Rico/8/34 (H1 N1) virus was studied. The highest activity was demonstrated by hydroxy-and fluorocontaining derivatives of 2,4,6-trimethoxybenzaldehyde [(12 i) and (13 i)].…”

Section: R E C O R D R E V I E W T H E C H E M I C a L R E C O R Dmentioning

confidence: 99%