Synthesis of Bismuth-Containing Polymer Films with High Refractive Index and X-ray Shielding Property by Radical Polymerization of Styrylbismuthine Derivatives

Abstract

Highly refractive and X-ray shielding polymer films were prepared by bulk radical copolymerization of diphenylstyrylbismuthine (MStBi) with tristyrylbismuthine (TStBi). For example, a yellow transparent film was obtained by copolymerization of MStBi and TStBi in a ratio of 70:30 (w/w). The refractive index (n D) and radiopacity of the film of these polymers are 1.72 and 1.60 μm-Al/μm-polymer, respectively. These properties are higher than those of the reported bismuth-containing polymers. The thermal stability and flexural module of the polymer films were controllable by the feed ratio of TStBi. The polymer films also exhibited high surface hardness and solvent resistance due to the rigid and cross-linked structure. The chemical and thermal stability and higher refractive index and radiopacity of the polymers suggest the potential applications for X-ray shielding of optical materials with high refractive indices.

Supramolecular Cross-Linking of Thiophenylene Polymers via Multiple Hydrogen Bonds toward High Refractive Index

“…A typical strategy for designing HRIPs is the introduction of highly polarizable and compact substituents, such as aromatics or sulfur, into the polymer. ,− Various high-refractive elements have been investigated, resulting in polymers containing uncommon substructures (heavy halogens, chalcogens, − and bismuth atoms, etc.) with higher RI (∼1.7–1.85).…”