Abstract:Allyl-functionalized copolymers with well-defined structure have been successfully prepared via selective reversible addition-fragmentation chain transfer (RAFT) copolymerization of styrene and allyl methacrylate possessing a higher reactive methacrylate and a lower reactive allyl. By employing a fast RAFT equilibrium, the polymerization for AMA completely occurred in methacrylate double bonds, whereas allyl double bonds remained intact and were introduced into the side-chains. GPC and 1H NMR analyses have con… Show more
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