Soft chemical synthesis is used to obtain a hydrangea-type bismuth
molybdate (Bi
2
MoO
6
) supercapattery electrode
that demonstrates considerable energy/power density and cycling life.
Structure and morphology studies, initially, reveal a phase-pure polycrystalline and hydrangea-type
surface appearance for Bi
2
MoO
6
, which upon testing
in an electrochemical energy storage system displays supercapattery
behavior, a combination of a supercapacitor and a battery. From the
power law, an applied-potential-dependent charge storage mechanism
is established for the Bi
2
MoO
6
electrode material.
A Trasatti plot evidences the presence of inner and outer surface
charges. The hydrangea-type Bi
2
MoO
6
electrode
demonstrates a specific capacitance of 485 F g
–1
at 5 A g
–1
and a stability of 82% over 5000 cycles.
An assembled symmetric supercapattery with a Bi
2
MoO
6
//Bi
2
MoO
6
configuration demonstrates
energy and power densities of 45.6 W h kg
–1
and
989 W kg
–1
, respectively. A demonstration elucidating
the lighting up of three light-emitting diodes, connected in series,
by the symmetric supercapattery signifies the practical potentiality
of the as-synthesized hydrangea-type Bi
2
MoO
6
electrode in energy storage devices.