Synthesis of (2,3-Naphthalocyaninato)ruthenium(II) and Reactions with Bidentate Ligands

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

“…Probably 5 also exists as a dimeric structure with a ruthenium-ruthenium double bond. The presence of such a ruthenium-ruthenium double bond has been reported for octaethylporphyrinato ruthenium [16,17], for PcRu [18,19] as well as for (tbu) 4 PcRu [4] and NcRu [5]. For metalloporphyrin dimeric complexes (only homometallic compounds) a molecular orbital (MO) diagram was described [20,21] The UV-vis spectrum of ((CH 3 ) 3 Si) 4 PcRu (5) recorded in dried and oxygen-free CH 2 Cl 2 under protected conditions shows a broad Q band at !…”

“…Later we developed a more convenient method for the preparation of pure PcRu via the corresponding bisisoquinoline complex PcRu(iqnl) 2 [2] which is readily available and can be thermally decomposed at 250°C with formation of pure PcRu [3]. Pure (tbu) 4 PcRu [4], (tbu) 4 NcRu [4] and NcRu [5] (Nc = 2,3-naphthalocyaninato) were also prepared by us using a similar method.…”

“…A tetra-trimethylsilyl-substituted phthalocyaninatoiron derivative has also been prepared recently [11]. Clpy) as the axial ligand L, because the chlorine atom in the 3-position lowers the coordination strength of pyridine [5].…”

Synthesis of Oligomeric Axially Bridged Ruthenium Phthalocyanines and 2,3-Naphthalocyanines

“…IR (KBr), Y (cm-I): 3049w, 2054s. 3,144.7,135.5,125.4,119.7,NQS 156.9,144.5,135.7,132.4,125.1,117.9. 1339s, 1285w, 1261w, 1200w, 1159m, 1128% 1103vs, 1034m, 1015m, 949w, 885m, 871w, 806w, 758s, 735m, 7 14m.…”

Metallomacrocycle (MacM) complex with cyanide as bridged ligand: Electronic structures of [MacMCN]n

“…The transition metals are Fe, Ru, Os, and Co; and other metals in the oxidation state +II were taken as central metals. The ligands (L) are linear π‐electron‐containing organic molecules bonded to the metal atom 15–26.…”