Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation

Soni, P. A.; Gupta, Pradeep Kumar; Maurya, Chandra Kant; Halve, Anand K.; Ganesan, K.

doi:10.1016/j.tetlet.2015.04.049

Cited by 5 publications

(1 citation statement)

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“…Usually by dehydration of diols, the α‐diketones were prepared often, but various methods have been put forward afterwards. Diverse metal catalysed such as, Pd, Ru, Fe, Cu, Mn, Au, Mo, Hg, used processes that have received considerable attention for the synthesis of α‐diketones from different sources. Despite this progress with transition metals, acid catalysts and oxidizing agents, were used in numerous methodologies by the researchers.…”

Section: Introductionmentioning

confidence: 99%

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

Tamuli

2018

ChemistrySelect

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The microwave assisted catalytic oxidation of olefins into diketones is a remarkable effort. A new metal free, efficient catalytic system was developed for the oxidation of alkenes into α‐diketones using KI‐I2‐DMSO under microwave irradiation. With various challenging functional groups such as stilbenes, simple alkenes, alkynes, phenanthrene and 1,4‐distyrylbenzene, this environment friendly approach afforded to its corresponding products in moderate to excellent yields in 5–12 minutes under the optimized condition. The resulting α‐diketone from chlorobenzil was found to undergo Suzuki‐Miyaura cross‐coupling reaction to obtain desired product in high yields. Thus, this methodology promises to be a cheaper and rapid synthesis for the production of different building blocks in the near future.

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Section: Introductionmentioning

confidence: 99%

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

Tamuli

2018

ChemistrySelect

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ChemInform Abstract: Synthesis of 1,2‐Diones from 1,2‐Diols Using Iron(III) Nitrate as Oxidant under Microwave Irradiation.

et al. 2015

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Gold catalyzed oxidation of vinyl acetylenes into vinyl & divinyl diketones and its synthetic application

Liang

Wang

Zou

et al. 2022

Tetrahedron Letters

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Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation

Cited by 5 publications

References 20 publications

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

ChemInform Abstract: Synthesis of 1,2‐Diones from 1,2‐Diols Using Iron(III) Nitrate as Oxidant under Microwave Irradiation.

Gold catalyzed oxidation of vinyl acetylenes into vinyl & divinyl diketones and its synthetic application

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Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation

Cited by 5 publications

References 20 publications

KI‐I2‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

KI‐I2‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

ChemInform Abstract: Synthesis of 1,2‐Diones from 1,2‐Diols Using Iron(III) Nitrate as Oxidant under Microwave Irradiation.

Gold catalyzed oxidation of vinyl acetylenes into vinyl & divinyl diketones and its synthetic application

Contact Info

Product

Resources

About

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones

KI‐I₂‐DMSO: An Improved Microwave‐Assisted Selective Oxidation of Alkenes into 1,2‐Diketones