Synthesis, crystal structure and third-order non-linear optical properties of two-dimensional supramolecular polymer [Co2(μ2-4,4′- bipy)2(μ2-be)2(be)2]n

Zhang, Zhaoxia; Li, Yong; Li, Kechang; Song, Wen‐Dong; Li, Qiu-Shun

doi:10.1016/j.inoche.2007.08.006

Cited by 13 publications

(1 citation statement)

References 25 publications

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“…Driven by intermolecularly reversible noncovalent interactions, supramolecular polymers have potential applications in developing and fabricating such new functional materials [1,2,3], as liquid crystalline and fibers exhibiting interesting properties arising from the dynamic nature of the noncovalent interactions. The driving force for the formation of supramolecular polymers by molecular self-assembly involves hydrogen bonding [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17], metal ligand coordination complexation [4,[18][19][20][21][22][23][24][25][26], - stacking interaction [4,[27][28][29][30][31][32][33], hydrophobic interaction [34,35] and host-guest interaction [4,[36][37][38][39].…”

Section: Introductionmentioning

confidence: 99%

Influence of the angle between two crown ether moieties on supramolecular copolymerization of bis(crown ether)s and bisparaquat homoditopic monomers

et al. 2010

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Bis(crown ether) homoditopic monomers containing two bis(p-phenylene)-34-crown-10 moieties with different angles (180 for monomer 3, 120 for monomer 4, and 60 for monomer 5) and a complementary bisparaquat homoditopic monomer (7) were designed and synthesized. The three bis(crown ether) monomers could organize into linear supramolecular polymers in concentrated solutions in CHCl 3 /CH 3 CN with the bisparaquat monomer 7, as demonstrated by 1 H NMR and viscosity studies. The pseudorotaxanes or supramolecular polymers formed from 3+7 and 4+7 had larger values of K a , p, n, slope 1, and slope 2 than those of 5+7. This result was attributed to the greater steric hindrance of compound 5 than that of 3 and 4, which resulted in less effective formation of linear supramolecular polymers from 5 with compound 7 than those from compounds 3 and 4 with compound 7, as also demonstrated by UV-vis method. bis(crown ether), bisparaquat homoditopic monomers, angle, supramolecular copolymerization

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Section: Introductionmentioning

confidence: 99%

Influence of the angle between two crown ether moieties on supramolecular copolymerization of bis(crown ether)s and bisparaquat homoditopic monomers

et al. 2010

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A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third‐Order NLO, and Fluorescence Properties

et al. 2012

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A new candidate [Cu(PPh3)2Him]Br (1, PPh3=triphenylphosphine, Him=1‐H‐imidazole) for nonlinear optical (NLO) materials has been synthesized and characterized crystallographically. The third‐order NLO optical properties were measured by the Z‐scan technique with an 8 ns pulsed laser at 532 nm. Compound 1 exhibits strong NLO absorptive abilities [α2=(61±5)×10−12] and effective self‐focusing performance [n2=(15±3)×10−18 m2·W−1] in 1.01×10−4 mol·dm−3 DMF solution. The compound also exhibits luminescence in DMF solution at room temperature and shows narrow emission with maximum at 382 nm. The electronic structure and photoluminescent process were investigated by means of TD‐DFT calculations. The results suggest that the contribution to the frontier orbitals from the CuBr δ bond plays a crucial role in its linear optical properties, and the origin of luminescence is attributable to the π∗︁→n transitions.

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Studies on two coordination polymers [M(μ4-pz25dc)]n (M=Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties

Liu

Deng

et al. 2009

Journal of Organometallic Chemistry

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Synthesis, crystal structure and third-order non-linear optical properties of two-dimensional supramolecular polymer [Co2(μ2-4,4′- bipy)2(μ2-be)2(be)2]n

Cited by 13 publications

References 25 publications

Influence of the angle between two crown ether moieties on supramolecular copolymerization of bis(crown ether)s and bisparaquat homoditopic monomers

Influence of the angle between two crown ether moieties on supramolecular copolymerization of bis(crown ether)s and bisparaquat homoditopic monomers

A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third‐Order NLO, and Fluorescence Properties

Studies on two coordination polymers [M(μ4-pz25dc)]n (M=Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties

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