Synthesis, crystal structure and nonlinear optical properties of a cluster compound containing the bipy ligand

Zhou, Jinhua; Li, Yi‐Zhi; Zheng, He‐Gen; Xin, Xinquan; Yin, Tao; Wang, Yuxiao; Ye, Song

doi:10.1023/b:tmch.0000019418.95492.bb

Cited by 9 publications

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“…Crystallographic data (excluding structure factors) for the structure reported in the paper have been deposited in the Cambridge Crystallographic Data Center as supplementary publication No. CCDC 211679 for (1) and No. 231783 for (2).…”

Section: Supplementary Materialsmentioning

confidence: 99%

“…The chemistry of transition metals Cu (Ag, Au) has been attracting considerable attention [1] because these compounds with interesting electronic, optical, structural and catalytic properties are of important biological and industrial significance in advanced materials, biological processes, and catalytic reactions [2,3]. Great interest in these compounds has recently been aroused by the search for better materials with thirdorder NLO properties because of their potential applications, not only in the protection of optical sensors and the human eye from high-intensity laser beams, but also in the development of optical signal detection techniques such as those utilized in optical computers and broad-band communication [4,5].…”

Section: Introductionmentioning

confidence: 99%

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Syntheses, Crystal Structures and Third-order Nonlinear Optical Properties of Coordination Polymers {[Et4N][Ag2I3]}n and [CuBr(C10H8N2S2)]n

Zhou

Chen

et al. 2005

Transition Met Chem

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Coordination polymers {[Et 4 N][Ag 2 I 3 ]} n (1) and [CuBr(C 10 H 8 N 2 S 2 )] n (2) were prepared by standard Schlenk techniques. Their X-ray measurements indicate that polymer (1) crystallizes in the orthorhombic space group Pnma, and polymer (2) crystallizes in the monoclinic space group P21/n. Complex (1) has a hanging ladder-like polymeric chain which can also be described as a helical chain bridged by Ag-Ag edges. Complex (2) exhibits a monoclinic crystal system with a slightly distorted tetrahedron. The nonlinear optical (NLO) properties of (1) and(2) were investigated by using Z-scan techniques with an 8 ns pulsed laser at 532 nm. These two coordination polymers exhibit NLO absorption and an effective self-focusing effect. The effective a 2 and n 2 values of cluster (1) are 3.04Â10 )11 m W )1 and 7.6Â10 )18 m 2 w )1 and the effective a 2 and n 2 values of compound (2) are 1.08Â10 )11 m W )1 and 3.1Â10 )18 m 2 w )1 when measured in CH 2 Cl 2 solution.

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Section: Supplementary Materialsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%