Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material:

Boughzala, Habib; Driss, Ahmed

doi:10.1155/2013/658939

Cited by 13 publications

(15 citation statements)

References 24 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The obtained spectra are shown in Fig. 7, indicating that the (C 6 N 2 H 7 S) 2 [SbCl 4 ]Cl exhibits two distinct absorption bands around 4.01 eV (310 nm) and 4.36 eV (285 nm) which are attributed to the metal charge transfer (LMCT) transition from the 3p orbital of Cl to 5p orbital of Sb(III) as described in previous outputs [35,[37][38][39]. On the other hand, the photoluminescence spectrum Fig.…”

Section: Optical Studysupporting

confidence: 52%

“…According to some studies reported in the literature [2,[27][28][29][30][31][32][33][34][35] we can propose an attempt of assignment of the observed bands Table 3.…”

Section: Infrared Spectroscopymentioning

confidence: 97%

“…Generally, in the caption 4 pyridiniumethioamide, the stretching vibrations C-H are detected in the region 2787-3133 cm −1 [28][29][30][31][32]. These vibrations are observed in IR at 3133, 2991, 2869 and 2787 cm −1 , where the two bands at 2904, 2869 cm −1 are attributed to the (C-H) asymmetric and symmetric stretching vibrations, respectively [33,34].…”

Section: Infrared Spectroscopymentioning

confidence: 98%

“…Hydrogen bonds between Free chlorine and organic entities in the crystal structure of (C 6 H 7 N 2 S) 2 [SbCl 4 ]Cl in projection along the c-axis. (H-bonds are represented by dashed lines) The atomic arrangement of (C 6 H 7 N 2 S) 2 [SbCl 4 ]Cl in projection along the b-axis 970-518 cm −1 and 764-416 cm −1 are attributed to the scissoring bending modes of C-C, C-N and C-NH 2[31,33,34].…”

mentioning

confidence: 99%

See 3 more Smart Citations

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

Elleuch

Fredj

Chniba-Boudjada

et al. 2019

J Inorg Organomet Polym

View full text Add to dashboard Cite

The new organic-inorganic hybrid material (C 6 H 7 N 2 S) 2 [SbCl 4 ]Cl was synthesized by slow evaporation method and characterized by single-crystal X-ray diffraction, infrared absorption, Hirshfeld surface analysis, optical absorption and photoluminescence measurements. The Centro symmetric compound crystallizes in the triclinic system of space group P1 with two formula units cell (Z = 2).The crystal structure is composed of a discrete [SbCl 4 ] − anion and two isolated chloride Cl − anions which carried the same negative charge to balance the total charge of this compound surrounded by the 4 pyridiniumethioamide cations. Organic and inorganic parts which are linked by means of hydrogen bonding contacts N-H···Cl with N···Cl length are varied in the range of 3.221-3.456 Å to form a Zero-dimensional network. The infrared study performed at room temperature charge in the 4000-400 cm −1 frequency regions confirms the existence of the organic cation [C 6 H 7 N 2 S] + and that of the [SbCl 4 ] − anion. The Photoluminescence spectrum exhibits a broad and strong band of luminescence located at 1.95 eV (635 nm), which can be even observed with the naked eye at room temperature and is due to exaction emission. The various intermolecular interactions of the two independent cations and six chloride atoms were examined via Hirshfeld surface analysis.Publisher's Note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

show abstract

Section: Optical Studysupporting

confidence: 52%

“…According to some studies reported in the literature [2,[27][28][29][30][31][32][33][34][35] we can propose an attempt of assignment of the observed bands Table 3.…”

Section: Infrared Spectroscopymentioning

confidence: 97%

Section: Infrared Spectroscopymentioning

confidence: 98%

mentioning

confidence: 99%

See 2 more Smart Citations

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

Elleuch

Fredj

Chniba-Boudjada

et al. 2019

J Inorg Organomet Polym

View full text Add to dashboard Cite

show abstract

“…32,35,39 For example, for a series of compounds containing , and BiI 6 3-anions, the lowest energy spectral feature assigned as LMCT is present at 231 nm (X = Cl) vs. 274 nm (X = Br) vs. 412 nm (X = I). 40 Thus, under the standard conditions of our aerobic synthesis, it can be inferred that iodide anions are complexed with the Bi 3+ ions until reduction and behave as non-innocent ligands in the reduction of Bi 3+ to form Bi NPs.…”

Section: Investigation Of the Mechanism Of Bi Np Formationmentioning

confidence: 99%

Aerobic method for the synthesis of nearly size-monodisperse bismuth nanoparticles from a redox non-innocent precursor

Winter¹,

Christopher-Allison²,

Brown³

et al. 2018

Nanotechnology

View full text Add to dashboard Cite

Herein, we report an aerobic synthesis method to produce bismuth nanoparticles (Bi NPs) with average diameters in the range 40-80 nm using commercially available bismuth triiodide (BiI 3 ) as starting material; the method uses only readily available chemicals and conventional laboratory equipment. Furthermore, size data from replicates of the synthesis under standard reaction conditions indicate that this method is highly reproducible in achieving Bi NP populations with low standard deviations in the mean diameters. We also investigated the mechanism of the reaction, which we determined results from the reduction of a soluble alkylammonium iodobismuthate precursor species formed in situ. Under appropriate concentration conditions of iodobismuthate anion, we demonstrate that burst nucleation of Bi NPs results from reduction of Bi 3+ by the coordinated, redox noninnocent iodide ligands when a threshold temperature is exceeded. Finally, we demonstrate phase transfer and silica coating of the Bi NPs, which results in stable aqueous colloids with retention of size, morphology, and colloidal stability. The resultant, high atomic number, hydrophilic Bi NPs prepared using this synthesis method have potential for application in emerging X-ray contrast and X-ray therapeutic applications.

show abstract

Synthesis, structural and electrical properties of two congruent isotypic diphosphates: Li2Na2P2O7 and Li3NaP2O7

2023

View full text Add to dashboard Cite

Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material:

Cited by 13 publications

References 24 publications

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

Aerobic method for the synthesis of nearly size-monodisperse bismuth nanoparticles from a redox non-innocent precursor

Synthesis, structural and electrical properties of two congruent isotypic diphosphates: Li2Na2P2O7 and Li3NaP2O7

Contact Info

Product

Resources

About