TiO 2 thin films were deposited on glass substrates by hydrolysis and condensation of tetraethyl orthotitanate [TEOT], and the pH of the solution is controlled by the addition of concentrated HNO 3 . The effect of thickness of the films on structural, optical, and photocatalytic properties has been investigated. The phase transformation temperature was determined by DTA-TGA; the nature of the phases and the crystallite size of TiO 2 are derived from X-ray diffraction patterns. From the transmittance spectra of the layers, the refractive index, and thickness were calculated using the envelope method. The results show that the films crystallize into anatase phase only with grains size in the range of 17 nm. The films showed high transmittance in the visible (93 %) and opaque in the UV. Finally, the as-prepared TiO 2 films exhibit high efficiency in the photocatalytic degradation of MB and RdB.