Synthesis, characterization of novel Nickel(II) complexes with PxNy-Type ligands and their application in reduction of ketones

Co‐Catalyzed Hydrosilylation of Ketones under Base‐Free Conditions: A Convenient Route to Silyl Ethers or Secondary Alcohols

“…The authors have cited additional references within the Supporting Information. [72][73][74][75][76][77][78][79][80][81][82][83][84][85]…”

Kappa what? Insights into the coordination modes of N2P2 ligands

“…A five-coordinate square-pyramidal Ni( ii ) complex bound κ 4 to the enantiomer of 7 catalyzed the hydrogenation of acetophenone derivatives including those with electron donating or withdrawing groups under milder conditions compared to those used by Ni(0)-bisphosphine complexes. 16 Most recently, a distorted tetrahedral Cu( i ) cation supported by 7 catalyzed the hydrosilylation of ketones under mild conditions. 17 Yields above 90% were reported for the hydrosilylation of aromatic ketones and some alkyl ketones yet the catalytic activity was cut by half when using sterically hindered 3-heptanone as a substrate.…”