Synthesis, characterization and thermal studies of 1,3-bis(4-pyridyl)propane bridged dicobaloximes

Yamuna, R.; Sarath, S; Kubandiran, K.; Umadevi, M.; Chakkaravarthi, G.

doi:10.1016/j.jorganchem.2016.03.015

Cited by 9 publications

(1 citation statement)

References 59 publications

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“…In addition, extra peaks are observed at 3419 cm −1 and 563 cm −1 . The peak at 3419 cm −1 corresponds to O−H … O group of the dioxime ligand and the peak at 563 cm −1 correspond to the Co−Br in the bromo cobaloxime complex [26] . All these characteristic peaks confirm the formation of the nanocomposite.…”

Section: Resultsmentioning

confidence: 82%

A Bifunctional Novel Bipyridine Bridged Dicobaloxime Complex for Electrochemical Proton Reduction and Toxic Metanil Yellow Dye Detection

Sundaresan,

Sowmya,

Vijaikanth

2024

ChemistrySelect

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A new bipyridine bridged dicobaloxime complex BrCo(dpgh)2(4,4’‐bipyridine)Co(dpgH)2Br was synthesized and characterized by standard spectroscopic techniques. The synthesized complex was employed as an electrocatalyst for the proton reduction in the presence of acetic acid as an acid source. The catalytic efficiency was calculated to be 0.379. Subsequently the nanocomposite of the complex was prepared with g‐C3N4 nanosheet by hydrothermal method and the composite material was characterized by standard physical characterization techniques. When the nanocomposite was employed as a catalyst for electrochemical sensing of toxic food color Metanil yellow dye using gold electrode, the LOD value was found to be 0.09 nM. These studies show that the dicobaloxime acts as a bifunctional catalyst towards electrochemical proton reduction and for the detection of Metanil yellow dye.

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Section: Resultsmentioning

confidence: 82%

A Bifunctional Novel Bipyridine Bridged Dicobaloxime Complex for Electrochemical Proton Reduction and Toxic Metanil Yellow Dye Detection

Sundaresan,

Sowmya,

Vijaikanth

2024

ChemistrySelect

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Cobaloxime Complex‐Mediated Organic Chemistry

Welker

2022

Patai's Chemistry of Functional Groups

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Cobaloxime complexes are now used to mediate a host of organic reactions. This chapter attempts to cover advances in this field which have occurred between 2000 and 2020. Topics range from the synthesis of new cobaloxime complexes which have been prepared for use in organic reactions to cobaloxime complex‐mediated or ‐assisted organic reactions. Reaction coverage includes, but is not limited to, cycloaddition and cyclization reactions, cross‐coupling reactions, carbonate synthesis and cobaloxime‐mediated oxidations and reductions including radical chemistry, and hydrogen production or removal using cobaloximes.

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A Study of Antimicrobial Activities and Cytotoxicity Effect on Human Liver Adenocarcinoma Using Cobaloxime Complexes

Amutha Selvi,

Dayalan

2023

Pharm Chem J

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Synthesis, characterization and thermal studies of 1,3-bis(4-pyridyl)propane bridged dicobaloximes

Cited by 9 publications

References 59 publications

A Bifunctional Novel Bipyridine Bridged Dicobaloxime Complex for Electrochemical Proton Reduction and Toxic Metanil Yellow Dye Detection

A Bifunctional Novel Bipyridine Bridged Dicobaloxime Complex for Electrochemical Proton Reduction and Toxic Metanil Yellow Dye Detection

Cobaloxime Complex‐Mediated Organic Chemistry

A Study of Antimicrobial Activities and Cytotoxicity Effect on Human Liver Adenocarcinoma Using Cobaloxime Complexes

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