Synthesis, characterization and preliminary reactivity behaviors with transitional metals of a new polydentate N-donor ligand

Syntheses, Crystal Structures, and Properties of Three Copper(II) Complexes Constructed by 4-(4,6-Bis(1H-pyrazol-1-yl)-1,3,5-triazin-2-yl)morpholine

“…All chemicals were obtained from commercial sources with reagent grade and used without further purification in the syntheses. The polydentate ligand L was prepared according to the literature . C, H and N analyses were carried out with a Vario elemental analysis III instrument.…”

“…In our previous study, we reported the polydentate ligand [4‐(4,6‐bis(1H‐pyrazol‐1‐yl)‐1,3,5‐triazin‐2‐yl)morpholine] (L) and its preliminary reactivity behaviors with transitional metals Co II , Mn II , Cr III , and Fe III . For the reason of coordination flexibility and superior properties of copper(II) complexes, we have synthesized three copper(II) complexes 1 – 3 of L with different counteranions in the presented report.…”

The crystal structure of bis(isothiocyanato-κ1N)-(methanol-κ1O)-[2-morpholine-4-yl-4,6-di(pyrazol-1-yl)-1,3,5-triazine-κ3N,N′,N′′] manganese(II), C16H18MnN10O2S2

“…2-Morpholine-4-yl-4,6-di(pyrazol-1-yl)-1,3,5-triazine (mpt) was prepared according to the literature [5]. A solution of mpt (0.1 mmol, 0.030 g) in methanol (2 mL) was added to a *Corresponding author: Jin-Feng Chu, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P.R.…”

Synthesis, X-ray Structure, Hirshfeld Analysis of Biologically Active Mn(II) Pincer Complexes Based on s-Triazine Ligands

“…In continuation to our interest with the s-triazine pincer complexes [21][22][23][24], and in light of the interesting recently reported data in literature [25][26][27][28][29][30][31], we are presenting here the synthesis of two new Mn(II) complexes with the s-triazine based NNN-pincer ligands shown in Figure 1. The structural In continuation to our interest with the s-triazine pincer complexes [21][22][23][24], and in light of the interesting recently reported data in literature [25][26][27][28][29][30][31], we are presenting here the synthesis of two new Mn(II) complexes with the s-triazine based NNN-pincer ligands shown in Figure 1. The structural features of both complexes are elucidated.…”