Synthesis, Characterization, and Hydrolytic Behavior of Diorganotin(IV) Coordination Polymers with Layered Structural Motifs

Shankar, Ravi; Singla, Nisha; Mendiratta, Swati; Kociok‐Köhn, Gabriele; Molloy, Kieran C.; Shestakova, Pavletta

doi:10.1002/ejic.201500652

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Cited by 4 publications

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“…Many research groups have been involved in the search of new molecules belonging to organo-and halotin (IV) families because of the various applications found for several molecules of these families [1][2][3][4][5][6]. In the continuation of our work in this field since many years, we have synthesized new phosphinato compounds from Me4NH2PO2 .…”

Section: Introductionmentioning

confidence: 99%

New Phosphinato Organo- And Halotin(iv) Derivatives, Adducts and Complexes: Synthesis and Spectroscopic Study

Mouhamadou

Sidibe

Diop

2020

JESR

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Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions.

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