Synthesis, Characterization and Analysis of Leishmanicide Ability of the Compound [Ru(Cl)&amp;lt;sub&amp;gt;3&amp;lt;/sub&amp;gt;(H&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;O)&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;(gly)]

Chagas, Marcio A. S.; Galvão, Anderson Dourado; Moraes, Fabricio Tarso de; Ribeiro, Augusto; Siqueira, A. B.; Salama, I. C. C. de Assis; Arrais-Silva, Wagner Welber; Sousa, K.M.D. de; Pereira, Claudia Cristina de Sousa; Santos, Wagner Batista dos

doi:10.4236/ojic.2017.74006

Cited by 7 publications

(4 citation statements)

References 19 publications

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“…The absorption band at 678 nm indicates the d-d transition of electrons in copper ions [32] . A similar result was obtained in [33].…”

Section: Uv Analysissupporting

confidence: 88%

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Kabdrakhmanova

Shaimardan

et al. 2023

Preprint

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At present, when the whole world is intensively switching to organic farming, the refusal or minimization of the usage of chemical plant protection products and synthesized fertilizers is a very urgent issue of the agro-industrial complex (AIC). Accordingly, the solution to the problems of increasing yields and ensuring the fight against pathogenic components should be carried out in accordance with the principles of "green" chemistry. In this regard, usage of mixed-ligand complexes based on carboxylic and amino acids with biogenic metals is dictated not only by their availability, low cost, and the ability to increase crop yields, but also by fungicidal activity, less toxicity, easily biodegradability, which lists them among the "green" ones and cost-effective plant biostimulants. In the present work, mixed ligand complex based on succinic acid, glycine and copper with the formula [Cu(succ)(gly)]n, was developed for usage as a fungicidal biostimulant, which has the ability to significantly reduce the number of pathogens. We have found that this compound has a layered structure and can increase soybean germination up to 100%.

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“…The absorption band at 678 nm indicates the d-d transition of electrons in copper ions [32] . A similar result was obtained in [33].…”

Section: Uv Analysissupporting

confidence: 88%

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Kabdrakhmanova

Shaimardan

et al. 2023

Preprint

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show abstract

“…The absorption band at 678 nm indicates the d-d transition of electrons in copper ions [42]. A similar result was obtained in [43].…”

Section: Uv Analysissupporting

confidence: 78%

Fungicidal and Stimulating Effects of Heteroleptic Copper Complex on the Germination and Phytosafety of Plants

Kabdrakhmanova,

Shaimardan

et al. 2023

J. Compos. Sci.

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At present, when the whole world is intensively switching to organic farming, the refusal or minimization of the usage of chemical plant protection products and synthesized fertilizers is a very urgent issue for the agro-industrial complex (AIC). Accordingly, the solution to the problems of increasing yields and ensuring the fight against pathogenic components should be carried out in accordance with the principles of “green” chemistry. In this regard, the usage of heteroleptic complexes based on carboxylic and amino acids with biogenic metals is dictated not only by their availability, low cost, and ability to increase crop yields but also by fungicidal activity, lower toxicity, and easy biodegradability, which lists them among the “green” and cost-effective plant biostimulants. In the present work, for the first time, a heteroleptic complex based on succinic acid and glycine, with the formula [Cu(succ)(gly)], was developed for usage as a fungicidal biostimulant, which has the ability to significantly reduce the number of pathogens. We found that this compound has a layered structure and was able to increase soybean germination up to 100%.

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“…To determine which isomer was synthesized by Chagas [8], computational methods were used to investigate the characteristics of each isomer compared to the experimental data. Table 1 shows the data obtained from the energy optimization of each isomer.…”

Section: Resultsmentioning

confidence: 99%

“…Analyzing the results in general, the fac-cis-diaquotrischloroglycinatoruthenium III isomer presented results suggesting that this was the molecule synthesized by Chagas [8].…”

Section: Discussionmentioning

confidence: 99%

Theoretical and Comparative Study of the Complex [RuCl3(H2O)2(Gly)] by Density Functional Theory

Sousa¹,

Chagas²,

Santos³

et al. 2018

OJIC

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In this work, the use of computational methods was essential to distinguish the three possible isomeric structures of the [RuCl 3 (H 2 O) 2 (Gly)] molecule. The characterization of these molecules was performed using IR, NMR and UV-VIS simulations. Some calculations related to the optimization of structures and properties such as chemical hardness and dipole moment were also conducted. The fac-cis isomer presented promising data when compared to the experimental data, indicating that this is the likely experimentally synthesized isomer. This study demonstrates the technical utility of the computational calculations by virtue of situations that prevent the realization of X-ray diffraction.

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Synthesis, Characterization and Analysis of Leishmanicide Ability of the Compound [Ru(Cl)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>(gly)]

Abstract: Studies of coordinated compounds containing ruthenium (Ru 2+ and Ru 3+

Cited by 7 publications

References 19 publications

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Fungicidal and Stimulating Effects of Heteroleptic Copper Complex on the Germination and Phytosafety of Plants

Theoretical and Comparative Study of the Complex [RuCl<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>(Gly)] by Density Functional Theory

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Synthesis, Characterization and Analysis of Leishmanicide Ability of the Compound [Ru(Cl)&lt;sub&gt;3&lt;/sub&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;2&lt;/sub&gt;(gly)]

Abstract: Studies of coordinated compounds containing ruthenium (Ru 2+ and Ru 3+

Cited by 7 publications

References 19 publications

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Multi-Ligand Copper Complex with Fungicidal and Stimulating Effect for Increasing the Germination and Phytosafety of Plants

Fungicidal and Stimulating Effects of Heteroleptic Copper Complex on the Germination and Phytosafety of Plants

Theoretical and Comparative Study of the Complex [RuCl&lt;sub&gt;3&lt;/sub&gt;(H&lt;sub&gt;2&lt;/sub&gt;O)&lt;sub&gt;2&lt;/sub&gt;(Gly)] by Density Functional Theory

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Synthesis, Characterization and Analysis of Leishmanicide Ability of the Compound [Ru(Cl)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>(gly)]

Theoretical and Comparative Study of the Complex [RuCl<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>(Gly)] by Density Functional Theory