Synthesis, Characterisation, and Performance Evaluation of Promoted Ni‐Based Catalysts for Thermocatalytic Decomposition of Methane

Abstract

Thermocatalyatic decomposition (TCD) of methane to CO X free hydrogen and carbon nanofibre (CNF) was investigated over a series of self-designed monometallic Ni catalyst and bimetallic NiÀ Cu and NiÀ Pd catalysts. The catalysts were synthesised from the wet impregnation method and characterised using a series of complementary techniques include TGA, XRD, BET, TPR, FESEM, TEM, and Raman Spectroscopy. Despite a substantial reduction of surface area in the promoted catalysts, the catalytic activity of the promoted catalyst was enhanced due to the nature of the process which is a metal-catalysed reaction. As a whole, bimetallic PdÀ Ni catalyst with a surface area of 2.76 m 2 g À 1 possesed the highest conversion of 77 % after 6 h reaction. The overall TCD reaction was found to be first-order with the calculated activation energy, E a of 38 kJ mol À 1. The methane consumption rates at 1023 K and 1073 K were 0.5 mol s À 1 g cat À 1 and 0.58 × 10 4 mol s À 1 g cat À 1 respectively. Meanwhile, the methane consumption rates improved considerably from 0.58 mol s À 1 g cat À 1 to 0.67 × 10 4 mol s À 1 g cat À 1 under the methane partial pressure of 41 kPa. The XRD profile of the fresh catalysts revealed that mixed oxides were formed over the surface of the support upon the addition of Cu and Pd to 50 % Ni/Al 2 O 3. Moreover, the formation of carbon nanofibers followed both tip and base growth mechanisms as evident from the TEM images. Larger and wider carbon fibres were found in the Pd promoted catalyst.

Syngas production employing nickel on alumina‐magnesia supported catalyst via dry methane reforming

“…In the spent catalyst, the graphitic carbon deposited has been indicated by the peaks corresponding to 2theta value of 26.6°, 44.8°and 51°[ICDD 03-065-6212], Figure 4. The results are in agreement with the existing literature [21,27,28].…”

Catalytic Decomposition of 2% Methanol in Methane over Metallic Catalyst by Fixed-Bed Catalytic Reactor

“…The calibrated data were used to calculate the concentrations of H 2 , N 2 , CH 3 OH, and CH 4 in the post-reaction gaseous mixture and, finally, the reactor was purged with N 2 and cooled to room temperature. The reactor configuration can be found in our previous paper [29].…”