“…In this type of structures the anion is not grafted to the inorganic layers by iono-covalent bonds to metal. Numerous organic molecules can be intercalated in the interlayer space via anion-exchange and form divers layered hybrids (Ghose, 1964;Stählin and Oswald, 1970;Petrov et al, 1989;Newman and Jones, 1999;Biswick et al, 2006;Arizaga et al, 2007;Rogez et al, 2011). Numerous studies were focused on the synthesis of transition-metal LHS, because of their interesting magnetic properties, which found out to be tunable by the type and the length of organic molecules, present as counter-ion (Rabu et al, 1993;Fujita and Awaga, 1996;Kurmoo et al, 2003;Forster et al, 2004;Kojima et al, 2007 ).…”