Integrative strategies to hybrid lamellar compounds: an integration challenge

Fernandes, Francisco M.; Baradari, H.; Sánchez, Clément

doi:10.1016/j.clay.2014.05.013

Cited by 52 publications

(27 citation statements)

References 273 publications

(299 reference statements)

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“…60 Clearly, the peculiar behavior of compound 1 can be explained by the competition between ferromagnetic and antiferromagnetic nearest neighbour exchange interactions. The best fit provides J = -0.40(1) cm -1 and g = 2.17 (1). The exchange interaction is significantly smaller (by two orders of magnitude) than the ones obtained by Fujita for a series of layered hydroxides containing aromatic sulfonates.…”

Section: Comparison With Classical Methods and Morphology Controlmentioning

confidence: 67%

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)

Evrard

Leuvrey

Farger

et al. 2018

Crystal Growth & Design

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HAL is a multidisciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

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Section: Comparison With Classical Methods and Morphology Controlmentioning

confidence: 67%

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)

Evrard

Leuvrey

Farger

et al. 2018

Crystal Growth & Design

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“…Clay–organic hybrids showed very early extraordinary importance in view to their industrial applications. In fact, they have been extensively used as additives and fillers in polymers (e.g., polymer–clay nanocomposites), rheological agents, specific sorbents, etc., and more recently in certain technological applications as advanced materials . As above signaled, seminal works from Gieseking, Hendricks, Bradley, and MacEwan developed in the 1940s were the basis for the current manufacture of the so‐called organoclays particularly produced in the two last decades .…”

Section: Modern Hybrids: a Mushrooming Multidisciplinary Field Of Resmentioning

confidence: 96%

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

Faustini

Nicole

Ruiz‐Hitzky

et al. 2018

Adv Funct Materials

302

228

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The rise of organic-inorganic hybrid materials in both academia and industry results from a convergence of diverse expertise and communities and is driven by the curiosity of open-minded scientists. In this review article, a historical perception on the evolution of hybrid material science is described. The major periods associated with the genesis of hybrid materials are discussed: prebiotic hybrid chemistry, hybrid materials made through know-how, the rise of silicates and silicon chemistry, modern hybrids: a mushrooming multidisciplinary field of research, and current applications of hybrid materials fully integrated in the society. Finally, the review presents an outlook that summarizes some future prospects related to hybrid materials.

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“…It is also essential to control the structural characteristics and the physical mechanisms influencing the properties of such new hierarchical nanostructures. [1,8,9,54,55] In many of the lamellar systems explored in the literature, such as bimetallic trioxalatometalates A[M II M III (ox) 3 ], [50][51][52][53][56][57][58][59] hexathiohypodiphosphates MPS 3 [47-49, 60, 61] [29,37,45,[62][63][64][65][66][67][68][69][70][71] the bond between organic species and inorganic network is weak (electrostatic interactions, hydrogen bonds). Therefore, interactions between properties are low and little synergy is obtained between electonic properties.…”

Section: Introductionmentioning

confidence: 99%

Hybrid interfaces in layered hydroxides: magnetic and multifunctional superstructures by design

Rabu¹,

Delahaye²,

Rogez³

2015

Nanotechnology Reviews

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The hybridization of simple transition metal hydroxides provides prototypical examples of layered magnetic and bifunctional hybrid materials in which the influence of the hybrid interface on the behavior of multiproperty systems can be evaluated. AbstractThis article is a critical review on layered hybrid organic-inorganic functional structures. We specially discuss series of results concerning the design of magnetic and multiproperty systems derived from hybridization of layered transition metal hydroxides. Series of hybrid materials showing original magnetic properties are reviewed, which were prepared by functionalization of layered simple hydroxides (LSH) of general formula M 2 (OH) 3 A (M = Co, Cu, Ni, Zn, ... and A = NO 3 -, OAc -, alkylcarboxylates, peptides, metal complexes...). To make the point on this vast family of hybrid compounds, we present first the work investigating the mechanism of interaction and the structural factors influencing the magnetic properties of hybrid materials based on LSH. Then we detail how even more complex anions can be immobilized and grafted into the interlamellar space giving rise to new functionalities. These systems are very good models for understanding the correlations between the structure of hybrid systems and the physical properties brought by the inorganic host and by the molecular moieties grafted onto the inorganic metal network. The interface between the organic and inorganic components, i.e. chemical bonding, charge density, or local pressure, is essential for the control of the properties of multifunctional hybrid systems. Some conclusions are drawn on the future of this approach, useful for developing new two-dimensional functional systems.

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Integrative strategies to hybrid lamellar compounds: an integration challenge

Cited by 52 publications

References 273 publications

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

Hybrid interfaces in layered hydroxides: magnetic and multifunctional superstructures by design

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Integrative strategies to hybrid lamellar compounds: an integration challenge

Cited by 52 publications

References 273 publications

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu2(OH)3(C12H25SO4)

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu2(OH)3(C12H25SO4)

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

Hybrid interfaces in layered hydroxides: magnetic and multifunctional superstructures by design

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Product

Resources

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Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)

Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu₂(OH)₃(C₁₂H₂₅SO₄)