Synthesis and Structure of La[B&lt;sub&gt;5&lt;/sub&gt;O&lt;sub&gt;8&lt;/sub&gt;(OH)(H&lt;sub&gt;2&lt;/sub&gt;O)]NO&lt;sub&gt;3&lt;/sub&gt;•2H&lt;sub&gt;2&lt;/sub&gt;O

Li, Linyan; Li, Guobao; Liao, Fuhui; Jian-Hua, Lin

doi:10.3866/pku.whxb20050714

Acta Physico-Chimica Sinica

2005

DOI: 10.3866/pku.whxb20050714

|View full text |Cite

Synthesis and Structure of La[B5O8(OH)(H2O)]NO3•2H2O

Linyan Li¹,

Guobao Li²,

Fuhui Liao³

et al.

Abstract: XYcduA^_'Z[q9a(klbqc 'def ghq'ijkl1mhqn'op(q(-rs%tuvzwnx(iycduz?{|}

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2013

2022

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 8 publications

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

et al. 2021

View full text Add to dashboard Cite

CrB4O6N kristallisiert in der nicht‐zentrosymmetrischen Raumgruppe P63mc (Nr. 186) mit den Gitterparametern a=5.1036(1), c=8.3519(3) Å und einem Volumen von 188,40(1) Å3. Synthetisiert durch ein Hochdruck‐/Hochtemperaturexperiment bei 7 GPa und 1673 K, repräsentiert die Phase das erste Hochdruck‐Oxonitridoborat. Strukturell zeigen sich sternförmige Einheiten bestehend aus vier BO3N‐Tetraedern, die in Analogie zu den homeotypen Nitridosilikaten MYbSi4N7 (M=Sr, Ba, Eu) durch ein gemeinsames vierfach koordiniertes Stickstoffatom miteinander verknüpft sind. Diese Einheiten bilden ein Netzwerk aus, in dessen Kanälen die Cr3+‐Ionen liegen. Im Gegensatz zu den trigonal‐planaren B(O/N)3‐Einheiten in allen anderen bekannten Oxonitridoboraten zeigt CrB4O6N erstmals tetraedrische Baueinheiten. Die strukturellen Zusammenhänge sowie die Ergebnisse der spektroskopischen Messungen und theoretischen Rechnungen am Chromoxonitridoborat werden im Folgenden erörtert.

show abstract

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

et al. 2021

View full text Add to dashboard Cite

show abstract

The First High‐Pressure Chromium Oxonitridoborate CrB₄O₆N—an Unexpected Link to Nitridosilicate Chemistry

et al. 2021

View full text Add to dashboard Cite

CrB4O6N crystallizes in the non‐centrosymmetric space group P63mc (no. 186) with the lattice parameters a=5.1036(1), c=8.3519(3) Å, and a volume of 188.40(1) Å3. It was synthesized in a high‐pressure/high‐temperature experiment at 7 GPa and 1673 K and represents the first high‐pressure oxonitridoborate. It is built up of starlike‐shaped entities of four BO3N tetrahedra, connected via one common nitrogen atom that resembles the fourfold‐coordinated nitrogen atoms in the homeotypic nitridosilicates MYbSi4N7 (M=Sr, Ba). Building up a network with channels that contain the Cr3+ ions, CrB4O6N contains for the first time a tetrahedral building unit in contrast to trigonal planar B(O/N)3 entities in all other known oxonitridoborates. The structural relations as well as the results of spectroscopic measurements and calculations on the chromium oxonitridoborate are discussed.

show abstract

Syntheses, Structure Elucidation, and Characterization of the Borate‐Nitrates RE[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O [RE = Nd (x = 0.85), Sm (x = 0)]

et al. 2016

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis and Structure of La[B<sub>5</sub>O<sub>8</sub>(OH)(H<sub>2</sub>O)]NO<sub>3</sub>•2H<sub>2</sub>O

Abstract: XYcduA^_'Z[q9a(klbqc 'def ghq'ijkl1mhqn'op(q(-rs%tuvzwnx(iycduz?{|}

Cited by 8 publications

References 0 publications

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

The First High‐Pressure Chromium Oxonitridoborate CrB₄O₆N—an Unexpected Link to Nitridosilicate Chemistry

Syntheses, Structure Elucidation, and Characterization of the Borate‐Nitrates RE[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O [RE = Nd (x = 0.85), Sm (x = 0)]

Contact Info

Product

Resources

About

Synthesis and Structure of La[B<sub>5</sub>O<sub>8</sub>(OH)(H<sub>2</sub>O)]NO<sub>3</sub>•2H<sub>2</sub>O

Abstract: XYcduA^_'Z[q9a(klbqc 'def ghq'ijkl1mhqn'op(q(-rs%tuvzwnx(iycduz?{|}

Cited by 8 publications

References 0 publications

Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

The First High‐Pressure Chromium Oxonitridoborate CrB4O6N—an Unexpected Link to Nitridosilicate Chemistry

Syntheses, Structure Elucidation, and Characterization of the Borate‐Nitrates RE[B5O8(OH)(H2O)x]NO3·2H2O [RE = Nd (x = 0.85), Sm (x = 0)]

Contact Info

Product

Resources

About

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

Das erste Hochdruck‐Chromoxonitridoborat CrB₄O₆N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

The First High‐Pressure Chromium Oxonitridoborate CrB₄O₆N—an Unexpected Link to Nitridosilicate Chemistry

Syntheses, Structure Elucidation, and Characterization of the Borate‐Nitrates RE[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O [RE = Nd (x = 0.85), Sm (x = 0)]