Synthesis and Structure of a Novel Ladder-Type Organobismuth Compound with Bismuth−Oxygen Interactions

Abstract

Hydrolysis of 6-tert-butyl-1-p-tolylbenzoxabismole (1) followed by self-condensation of hydroxybismuthine (3) gave the corresponding dibismuth oxide 2, which was found by X-ray crystallographic analysis to exhibit a dimeric form with a novel ladder type by both inter-and intramolecular Bi-O interactions.

A mini review on chemical fixation of CO2: Absorption and catalytic conversion into cyclic carbonates

“…[5][6][7][8]. In the past decade, there has been a rapid development on bismuth chemistry [9][10][11][12][13][14][15][16][17]. There are various researches on novel cationic organobismuth complexes and their applications [16][17][18][19][20][21][22][23].…”

Anionic Bismuth Oxido Clusters with Pendant Silver Cations: Synthesis and Structures of {[Bi4(µ3‐O)2(TFA)9Ag(tol)2]2} and {Bi4(µ3‐O)2(TFA)10(AgPPh3)2}n

“…For these bismuth atoms, there are three η 1 ‐carboxylate and one η 2 ‐carboxylate ligands occupying the five pentagonal sites. Other heterometallic Bi 4 (µ 3 ‐O) 2 compounds such as Na[Bi 4 (µ 3 ‐O) 2 (OC 6 F 5 ) 9 (C 4 H 8 O) 2 ] and Li 2 [Bi 4 (µ 3 ‐O) 2 { O ‐2‐(CH 2 CH=CH 2 )C 6 H 4 } 10 ] exhibit distortion of the core due to the effects of the presence of non‐bismuth metal ions that bind to the oxido ligands, which causes distortion from planarity , , . A comparison of the Bi hinge –O and Bi wingtip –O distances in similar compounds is given in Table .…”

“…Other heterometal- [35] exhibit distortion of the core due to the effects of the presence of non-bismuth metal ions that bind to the oxido ligands, which causes distortion from planarity. [33,40,41] A comparison of the Bi hinge -O and Bi wingtip -O distances in similar compounds is given in Table 3. In all of these compounds, the Bi-O oxide distances are considerably shorter (ca.…”

Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds

“…In order to construct new organobismuth compounds by taking the advantage of the combination of multiple inter- and intramolecular Bi-O interactions [ 39 ], a novel structure which presented a ladder-type was achieved by Uchiyama and co-workers [ 40 ]. Three 1,3,2,4-dioxadibismetane rings successfully comprised this special framework by both inter- and intramolecular Bi–O interactions.…”