We found that self-determining collimated light is generated in a photonic crystal fabricated on silicon. The divergence of the collimated beam is insensitive to that of the incident beam and much smaller than the divergence that would be generated in conventional Gaussian optics. The incident-angle dependence of the self-collimated light propagation including lens-like divergent propagation was interpreted in terms of the highly modulated dispersion surfaces with inflection points, where the curvature changes from downward to upward corresponding to respectively a concave/convex-lens case. This demonstration is an important step towards controlling beam profile in photonic crystal integrated light circuits and towards developing “photonic crystalline optics.”

No abstract

No abstract

A boron-substituted azobenzene, (E)-[2-(4-methoxyphenylazo)phenyl]bis(pentafluorophenyl)borane, presented the most intense fluorescence among the azobenzene derivatives.

The phosphonium borane [p-Mes(2)B(C(6)H(4))PMePh(2)](+) complexes fluoride in water containing 10% methanol with a binding constant of 1.0(+/-0.1) x 10(3) M(-1) to afford the zwitterion p-Mes(2)FB(C(6)H(4))PMePh(2).