“…In all complexes the Pd(II) ion is nearly planar, fourfold environment. The thione C_S bond in the coordinated anionic ligands becomes formally a single bond making it longer (average = 1.7418 Å) than the C_S bond of the neutral moieties [24,25], and the N(2)\C bond (average 1.3252 Å) (Fig. 2, Table 2), which becomes a double bond in the anionic moieties, is typical for C_N distances [44].…”