Synthesis and spectroscopy of binuclear phosphine bridged palladium hydrides: Pd2HX3[dppm]2 (X=Br, I; dppm=bis[diphenylphosphino]methane)

a b s t r a c tNovel dinuclear palladium complexes having two isocyanide ligands were synthesized by using a binucleating ligand, N,N 0 -bis[2-(diphenylphsphino)phenyl]formamidinate (dpfam). The structure of [Pd 2 (l-dpfam)(tert-BuNC) 2 ]Cl was confirmed by X-ray analysis, showing that the Pd-Pd bond length of 2.5824(3) Å falls well within the range of those for known dipalladium complexes having the edge-sharing structure and two isocyanides coordinate to palladium in almost parallel and in close proximity. The dinuclear complex [Pd 2 (l-dpfam)(tert-BuNC) 2 ]PF 6 served as catalyst for pyrrole formation from tertbutylisocyanide and various alkynes.

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Synthesis and spectroscopy of binuclear phosphine bridged palladium hydrides: Pd2HX3[dppm]2 (X=Br, I; dppm=bis[diphenylphosphino]methane)

Cited by 4 publications

References 28 publications

Non‐optical Method in Configuration Study

Non‐optical Method in Configuration Study

The chemistry of binuclear palladium(II) and platinum(II) complexes

Synthesis of dinuclear palladium complexes having two parallel isocyanide ligands, and their application as catalysts to pyrrole formation from tert-butylisocyanide and alkynes

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