Synthesis and spectral studies of diorganotin heterocyclic dithiocarbamate complexes and crystal structures of (2-F-Bz)2Sn(Cl) S2CN(CH2CH2)2NEt and (3-Cl-Bz)2Sn [S2CN(CH2CH2)2NEt]2 ⋅ 0.5HN(CH2CH2)2NH

The uses and potential utility of tin/organotin dithiocarbamate, − S 2 CNR 2 , compounds are reviewed. Various derivatives exhibit exciting potential as anti-cancer agents, anti-microbial agents and insecticides, e.g. against mosquito larvae. Tin dithiocarbamates have also proven useful as precursors for tin sulfide nanoparticles. There is a wealth of structural data available for such compounds and with the exception of the diorganotin bis(dithiocarbamate) compounds, R 2 Sn(S 2 CNR 2 ) 2 , compounds for which different structural motifs are evident, there is a certain degree of homogeneity in the molecular structures for each class of compound unless there are additional coordination sites on the R and/or R groups. Owing to the strong coordination potential of the dithiocarbamate ligand for tin, supramolecular aggregates involving secondary Sn· · ·S interactions are the exception rather than the norm.

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Tin dithiocarbamates: applications and structures

Tiekink

2008

Applied Organom Chemis

192

153

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Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

Rehman

Barsan

Wharf

et al. 2008

Inorganica Chimica Acta

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Molecular structures and supramolecular association of chlorodiorganotin(IV) complexes with bis- and tris-dithiocarbamate ligand

Tlahuext

Reyes-Martínez

Vargas-Pineda

et al. 2011

Journal of Organometallic Chemistry

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Synthesis and spectral studies of diorganotin heterocyclic dithiocarbamate complexes and crystal structures of (2-F-Bz)2Sn(Cl) S2CN(CH2CH2)2NEt and (3-Cl-Bz)2Sn [S2CN(CH2CH2)2NEt]2 ⋅ 0.5HN(CH2CH2)2NH

Abstract: Some new diorganotin

Cited by 9 publications

References 18 publications

Tin dithiocarbamates: applications and structures

Tin dithiocarbamates: applications and structures

Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

Molecular structures and supramolecular association of chlorodiorganotin(IV) complexes with bis- and tris-dithiocarbamate ligand

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