2008
DOI: 10.1016/j.jcrysgro.2007.09.036
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Synthesis and spectral properties of starch capped CdS nanoparticles in aqueous solution

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Cited by 56 publications
(29 citation statements)
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“…For the nanoparticle synthesis in the second method, polysaccharides such as native starch (Rodriguez et al 2008), soluble starch (Chairam et al 2009;Li et al 2007;Ma et al 2009;Radhakrishnan et al 2007;Vigneshwaran et al 2006;Wei et al 2004), and CMC Liu et al 2011a;Yu et al 2009;Zheng et al 2009a) have been shown to be good stabilizers. Polysaccharides can form complexes with divalent metal ions due to their high number of coordinating functional groups (hydroxyl and glucoside groups) (Taubert and Wegner 2002) and present dynamic supramolecular associations facilitated by inter-and intramolecular hydrogen bonding, which can act as templates for metal nanoparticle growth (Raveendran et al 2003).…”
Section: Nanofillers and Preparation Techniquesmentioning
confidence: 99%
“…For the nanoparticle synthesis in the second method, polysaccharides such as native starch (Rodriguez et al 2008), soluble starch (Chairam et al 2009;Li et al 2007;Ma et al 2009;Radhakrishnan et al 2007;Vigneshwaran et al 2006;Wei et al 2004), and CMC Liu et al 2011a;Yu et al 2009;Zheng et al 2009a) have been shown to be good stabilizers. Polysaccharides can form complexes with divalent metal ions due to their high number of coordinating functional groups (hydroxyl and glucoside groups) (Taubert and Wegner 2002) and present dynamic supramolecular associations facilitated by inter-and intramolecular hydrogen bonding, which can act as templates for metal nanoparticle growth (Raveendran et al 2003).…”
Section: Nanofillers and Preparation Techniquesmentioning
confidence: 99%
“…The hydroxyl groups of the starch act as the coordination site for the release of the metal ions and hence control the chemical reaction rate of M 2+ and Se 2-to produce MSe. These hydroxyl groups also act as passivating centres for stabilisation and solubility of the as-synthesized nanoparticles in water, while the free aldehyde group on one end of a starch polymer could also act as conjugation site for further functionalization which makes it easier for its biological applications (Raveendran et al, 2003;, Mishra et al, 2009;Rodriguez et al, 2008).…”
Section: Reaction Mechanismsmentioning
confidence: 99%
“…Recently, biopolymers, such as chitosan [4][5][6][7], alginate [8][9][10][11] and starch [12][13][14][15][16][17][18][19][20][21][22][23][24] have been introduced as capping agents and/ or matrices for semiconductor, metal and semiconductorsemiconductor core-shell nanoparticles. Because macromolecular chains of these biopolymers possess a large number of hydroxyl groups, they can complex well with metal ions, which further enables a good control of size, shape and dispersion of the nanoparticles formed.…”
Section: Introductionmentioning
confidence: 99%