Abstract:Hydrogel nanocomposites containing silver nanoparticles of size 15–21 nm were prepared by diffusion and in-situ chemical reduction in chemically crosslinked polymers based on N-acryloyl-N′-ethyl piperazine (AcrNEP) and N-isopropylacrylamide (NIPAM). The polymer chains of the hydrogel network offered control and stabilization of silver nanoparticles without the need for additional stabilizers. The presence of silver nanoparticles and their size was quantified by UV-Vis absorption spectroscopy and scanning elect… Show more
“…Researchers are amazed by the possibility to produce gold and silver nanoparticles with specific morphology and surface functionalization, leading to new properties [43][44][45]. Moreover, advanced characterization methods allow one to study their capability to respond to changes in pH, redox potentials, temperature, light and magnetic fields [46][47][48][49][50][51].…”
This review provides an up-to-date overview on silver nanoparticles-based materials suitable as optical sensors for water pollutants. The topic is really hot considering the implications for human health and environment due to water pollutants. In fact, the pollutants present in the water disturb the spontaneity of life-related mechanisms, such as the synthesis of cellular constituents and the transport of nutrients into cells, and this causes long / short-term diseases. For this reason, research continuously tends to develop always innovative, selective and efficient processes / technologies to remove pollutants from water. In this paper we will report on the silver nanoparticles synthesis, paying attention to the stabilizers and mostly used ligands, to the characterizations, to the properties and applications as colorimetric sensors for water pollutants. As water pollutants our attention will be focused on several heavy metals ions, such as Hg(II), Ni(II),Cu(II), Fe(III), Mn(II), Cr(III/V) Co(II) Cd(II), Pb(II), due to their dangerous effects on human health. In addition, several systems based on silver nanoparticles employed as pesticides colorimetric sensors in water will be also discussed. All of this with the aim to provide to readers a guide about recent advanced silver nanomaterials, used as colorimetric sensors in water.
“…Researchers are amazed by the possibility to produce gold and silver nanoparticles with specific morphology and surface functionalization, leading to new properties [43][44][45]. Moreover, advanced characterization methods allow one to study their capability to respond to changes in pH, redox potentials, temperature, light and magnetic fields [46][47][48][49][50][51].…”
This review provides an up-to-date overview on silver nanoparticles-based materials suitable as optical sensors for water pollutants. The topic is really hot considering the implications for human health and environment due to water pollutants. In fact, the pollutants present in the water disturb the spontaneity of life-related mechanisms, such as the synthesis of cellular constituents and the transport of nutrients into cells, and this causes long / short-term diseases. For this reason, research continuously tends to develop always innovative, selective and efficient processes / technologies to remove pollutants from water. In this paper we will report on the silver nanoparticles synthesis, paying attention to the stabilizers and mostly used ligands, to the characterizations, to the properties and applications as colorimetric sensors for water pollutants. As water pollutants our attention will be focused on several heavy metals ions, such as Hg(II), Ni(II),Cu(II), Fe(III), Mn(II), Cr(III/V) Co(II) Cd(II), Pb(II), due to their dangerous effects on human health. In addition, several systems based on silver nanoparticles employed as pesticides colorimetric sensors in water will be also discussed. All of this with the aim to provide to readers a guide about recent advanced silver nanomaterials, used as colorimetric sensors in water.
“…A greener approach has also been adopted by Bajpai and Kumari by using clove extract as the natural reducing agent [54]. Typically, the composite hydrogel will turn from colorless to yellowish-brown upon the formation of Ag NPs [55]. In this approach, the problem of NPs aggregation could be avoided, as the free space within the hydrogel porous structure offers a nanoscopic pot for the synthesis of NPs [50].…”
Section: Synthesis Methods Of Noble Metal Nps–hydrogels Compositesmentioning
Challenges in organ transplantation such as high organ demand and biocompatibility issues have led scientists in the field of tissue engineering and regenerative medicine to work on the use of scaffolds as an alternative to transplantation. Among different types of scaffolds, polymeric hydrogel scaffolds have received considerable attention because of their biocompatibility and structural similarity to native tissues. However, hydrogel scaffolds have several limitations, such as weak mechanical property and a lack of bioactive property. On the other hand, noble metal particles, particularly gold (Au) and silver (Ag) nanoparticles (NPs), can be incorporated into the hydrogel matrix to form NP–hydrogel composite scaffolds with enhanced physical and biological properties. This review aims to highlight the potential of these hybrid materials in tissue engineering applications. Additionally, the main approaches that have been used for the synthesis of NP–hydrogel composites and the possible limitations and challenges associated with the application of these materials are discussed.
“…The development of nontoxic nanocomposite hydrogels containing silver nanoparticles is an active area of research, and the synthesis of silver nanoparticles in microgels and hydrogels using various chemical methods has been documented in the literature [3].…”
A theoretical analysis of the influence of the flow of a coolant containing silver nanoparticle (Ag) in an automotive radiator is presented. The coolant fluid is composed of water or an aqueous solution of Ethylene-Glycol (EG50%) and silver nanoparticles. Ethylene glycol (EG) has been used in automobile radiators for many years due to its compatibility with metals and its anti-cooling properties. Silver nanoparticles are being incorporated into the development of high-precision surgical equipment. It is shown that the rate of heat transfer increases significantly using silver nanoparticles and ethylene glycol and water. There is a maximum for heat exchange between fluids in all analyzed coolant flows-the maximum moves to higher airflow rates when the coolant flow rate is increased. However, the energy dissipation in the stream also increases, but the relationship between the energy dissipated in the flow and the energy transferred in the form of heat is low, which justifies the use of silver nanoparticles and ethylene glycol, or silver nanoparticles and water as a coolant in the automotive vehicle radiator.
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