“…It now reacts with ammonium acetate to form the imine intermediate ( III ). 42,43 At the same time, aldehyde can react with an excess of ammonium acetate to form a Schiff base IV . 44–48 Schiff base IV is able to react with intermediate ( III ) by intermolecular cyclization to form intermediate V .…”
A one-pot multicomponent procedure for the efficient synthesis of benzimidazole derivatives via coupling of benzo-1,2-quinone, aldehydes, and ammonium acetate using an Fe(iii)-porphyrin catalyst system is presented.
“…It now reacts with ammonium acetate to form the imine intermediate ( III ). 42,43 At the same time, aldehyde can react with an excess of ammonium acetate to form a Schiff base IV . 44–48 Schiff base IV is able to react with intermediate ( III ) by intermolecular cyclization to form intermediate V .…”
A one-pot multicomponent procedure for the efficient synthesis of benzimidazole derivatives via coupling of benzo-1,2-quinone, aldehydes, and ammonium acetate using an Fe(iii)-porphyrin catalyst system is presented.
“…General 2-Amino-4,6-di-tert-butylphenol was prepared according to a previously described procedures. 23 Solvents were puried by standard methods. 24 All synthesis have been conducted in evacuated ampoules.…”
The novel benzoxazole I undergoes a fast intramolecular decyclization and demonstrates either a neutral or anionic coordination type in cadmium complexes.
“…Crystals of (I) were prepared by a recently described method (Lodyato et al, 2003, Vinšová et al, 2006. Purification was by column chromatography on silica gel using ethyl acetate-petroleum ether (1:9 v/v) as eluent.…”
The multiple‐bond character of the C—C bond connecting the pyridine and benzoxazole ring systems results in an overall planarity of the central aromatic part of the title compound, C20H24N2O. The crystal structure is stabilized by intermolecular C—H...N close contacts, linking molecules into layers.
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