2012
DOI: 10.1016/j.jallcom.2012.03.112
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Synthesis and photoluminescence of semiconductor ZnSe hollow microspheres by two-sourced evaporation

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Cited by 34 publications
(11 citation statements)
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“…Following the demonstration of possible application of zinc selenide in photoelectronic devices, an intensive attention is paid to ZnSe as an alternative to the more toxic Cd-based materials. Indeed, ZnSe-based materials in such forms as thin films, nanocrystals (NCs), quantum wells, flower-shaped nanocrystals [1], nanoribbons [2], nanowires [3], hollow microspheres [4] and bulk crystals are applicable for fabrication of blue and green light-emitting diodes due to the direct band gap, infrared windows due to wide transmission wavelength range, lenses and prisms, and optically controlled switching devices due to giant photoresistivity.…”
Section: Introductionmentioning
confidence: 99%
“…Following the demonstration of possible application of zinc selenide in photoelectronic devices, an intensive attention is paid to ZnSe as an alternative to the more toxic Cd-based materials. Indeed, ZnSe-based materials in such forms as thin films, nanocrystals (NCs), quantum wells, flower-shaped nanocrystals [1], nanoribbons [2], nanowires [3], hollow microspheres [4] and bulk crystals are applicable for fabrication of blue and green light-emitting diodes due to the direct band gap, infrared windows due to wide transmission wavelength range, lenses and prisms, and optically controlled switching devices due to giant photoresistivity.…”
Section: Introductionmentioning
confidence: 99%
“…ZnSe nanostructures have been achieved by several methods, such as thermochemical method [8], atomic layer deposition method [11], solvothermal processes [12], and hydrothermal method [13]. In hydrothermal and solvothermal processes, the morphology of the as-grown samples can be easily influenced by some additives such as ethylene diamine tetraacetic acid (EDTA) [14], diethanolamine [15], and hydrazine hydrate (N 2 H 4 Á 2H 2 O) [16].…”
Section: Introductionmentioning
confidence: 99%
“…12 [39,44,45]. The emission bands at 398 nm, 416 nm, and 496 nm are usually assigned to self-activated luminescence, probably as a result of some donor-acceptor pairs related to Zn/Se-vacancies and interstitial states [28,30,46]. Besides, the emission bands gap energy may be attributed to the differences of shapes or sizes of ZnSe crystal.…”
Section: Optical Propertiesmentioning
confidence: 99%
“…Moreover, solvents, organic additives, and surfactants have important effects on the shape-and sizecontrolled synthesis of inorganic particles [23][24][25][26][27]. Although a few contributions have appeared on the synthesis of various morphological ZnSe, including hollow nanospheres/microspheres, nanowires, nanobelts and branched heterostructure, nanorods, flowerlike, and so forth [28][29][30][31][32][33][34][35][36][37][38][39], there have been few studies on fabrication of ZnSe spheres via surfactant-assisted solvothermal method. Herein, in this paper, we report a facile, convenient, and reliable solvothermal method to synthesis stilleite structure ZnSe microspheres.…”
Section: Introductionmentioning
confidence: 99%