Synthesis and magnetic property of porous naphthalenetetracarboxylate manganese complex, the first (μ2-aqua)bis(μ2-carboxylate)-bridged manganese polymer

Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity

“…We believe that these two principles, stable 3D framework structure and electron stabilization mechanism, can be transferable to other systems. According to our analysis, it is expected that some other compounds, such as M 2 (C 14 H 4 O 8 )$(H 2 O) 2 (M = Zn, Mn, Ca), 36,37 38 and M(NDC)$(H 2 O) (M = Mn, Zn or Cd, NDC = 2,6-naphthalenedicarboxylate), 39 can also serve as high-capacity electrode materials for energy storage.…”

1D Tube, 2D Layer, and 3D Framework Derived from a New Series of Metal(II)−5-Aminodiacetic Isophthalate Coordination Polymers

“…Furthermore, the new tetracarboxylate ligands, 3,3‘,4,4‘-benzophenonetetracarboxylate 1a and 1,4,5,8-naphthalenetetracarboxylate, were also reported recently. However, the carboxyl groups on the above-mentioned aromatic rings are all rigid, which to some degree limit the outspread in 3D direction of metal−organic frameworks and hinder the assembly of certain crystalline products 6a…”

“…As an important family of multidentate O-donor ligands, organic aromatic tetracarboxylate ligands, such as 1,2,4,5-benzenetetracarboxylate (1,2,4,5-btec), have been extensively employed in the preparation of such metal−organic compounds . Furthermore, the new tetracarboxylate ligands, 3,3‘,4,4‘-benzophenonetetracarboxylate 1a and 1,4,5,8-naphthalenetetracarboxylate, were also reported recently. However, the carboxyl groups on the above-mentioned aromatic rings are all rigid, which to some degree limit the outspread in 3D direction of metal−organic frameworks and hinder the assembly of certain crystalline products 6a…”

Copper(II) coordination polymer based on l-arginine as a supramolecular hybrid inorganic–organic material: synthesis, structural, spectroscopic and magnetic properties

“…1,2,4-triazole) [10] and carboxylic or dicarboxylic acids [11,12]. Recent studies have showed that the carboxylate O-donors of amino acid are important linkers in the chemistry of homo-and heterometallic coordination polymers [13][14][15][16][17][18][19][20][21][22][23]. The carboxylate linkers represent an abundant group characterized by diversity, multifunctionality and overall stability.…”

“…The carboxylate linkers represent an abundant group characterized by diversity, multifunctionality and overall stability. They display a great variety of coordination modes ranging from basic η 1 :η 0 , η 1 :η 1 , μ 2 −η 2 :η 0 , μ 3 −η 3 :η 0 , syn−syn−μ 2 −η 1 :η 1 , anti−anti−μ 2 −η 1 :η 1 , syn −anti−μ 2 −η 1 :η 1 and mixed μ 2 −η 2 :η 1 , μ 3 −η 2 :η 2 , μ 4 −η 2 :η 2 and μ 5 −η 3 :η 3 [24] and can extend the building blocks into one, two and three dimensions [13][14][15][16][17][18][19][20][21][22][23]. Among the coordination modes, the syn−syn, anti−anti and syn−anti conformations favour the formation of polymeric chains.…”