1999
DOI: 10.1002/(sici)1097-0126(199909)48:9<851::aid-pi228>3.0.co;2-z
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Synthesis and lithographic characterization of poly[(dihydrocarveol)-co-(1,1-dimethylethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate)-co-(maleic anhydride)]

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“…4 wt %) occur below 170 °C because of the associated waters of hydration. All the metalloconstructs are stable up to 170 °C, but slightly above 190 °C, 7 expels 2‐methylpropene;45 this is a well‐documented thermal elimination process for tert ‐butyl esters46 (this thermal elimination has been used to quantify dendron attachment to silica47). The mass loss for 7 has been estimated to be about 12 wt %, which compares well with the theoretically calculated tert ‐butyl group mass loss (12.8 wt %).…”
Section: Resultsmentioning
confidence: 99%
“…4 wt %) occur below 170 °C because of the associated waters of hydration. All the metalloconstructs are stable up to 170 °C, but slightly above 190 °C, 7 expels 2‐methylpropene;45 this is a well‐documented thermal elimination process for tert ‐butyl esters46 (this thermal elimination has been used to quantify dendron attachment to silica47). The mass loss for 7 has been estimated to be about 12 wt %, which compares well with the theoretically calculated tert ‐butyl group mass loss (12.8 wt %).…”
Section: Resultsmentioning
confidence: 99%