Synthesis and functionality of transition metal-centered polyoxometalate-based crystalline framework materials

Lan, Qing; Jin, Sujuan; Zhang, Zhiming

doi:10.1360/n972018-00636

Cited by 5 publications

(1 citation statement)

References 20 publications

(21 reference statements)

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“…Polyoxometalates (POMs) are a class of early transition metal anionic clusters with highly negative charges, strong stability, and tunable redox properties, which have been attracting considerable interests in their numerous applications in catalysis, magnetism, and energy conversion . Accompanying with, POM‐based extended structures such as transition metal‐substituted POMs, sulfate‐centered Preyssler‐type POMs, and vanadium‐capped POMs have also been explored with promising performances.…”

Section: Introductionmentioning

confidence: 99%

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Xiao

Zhou

Tong

et al. 2019

Chemistry An Asian Journal

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To increase the conductivity of polyoxometalate‐based metal–organic frameworks (POMOFs) and promote their applications in the field of energy storage, herein, a simple approach was employed to improve their overall electrochemical performances by introducing a functionalized single‐walled carbon nanotubes (SWNT‐COOH). A new POMOF compound, [Cu18(trz)12Cl3(H2O)2][PW12O40] (CuPW), was successfully synthesized, then the size‐matched functionalized SWNT–COOH was introduced to fabricate CuPW/SWNT–COOH composite (PMNT–COOH) by employing a simple sonication‐driven periodic functionalization strategy. When the PMNT–COOH nanocomposite was used as the anode material for Lithium‐ion batteries (LIBs), PMNT–COOH(3) (CuPWNC:SWNT‐COOH=3:1) showed superior behavior of energy storage, a high reversible capacity of 885 mA h g−1 up to a cycle life of 170 cycles. The electrochemical results indicate that the uniform packing of SWNT–COOH provided a favored contact between the electrolyte and the electrode, resulting in enhanced specific capacity during lithium insertion/extraction process. This fabrication of PMNT–COOH nanocomposite opens new avenues for the design and synthesis of new generation electrode materials for LIBs.

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Section: Introductionmentioning

confidence: 99%

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Xiao

Zhou

Tong

et al. 2019

Chemistry An Asian Journal

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Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction

Song

Peng

Yao

et al. 2022

Chinese Chemical Letters

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Enhancing catalytic aerobic oxidation performance of cyclohexaneviasize regulation of mixed-valence {V₁₆} cluster-based metal–organic frameworks

et al. 2019

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Synthesis and functionality of transition metal-centered polyoxometalate-based crystalline framework materials

Cited by 5 publications

References 20 publications

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction

Enhancing catalytic aerobic oxidation performance of cyclohexaneviasize regulation of mixed-valence {V₁₆} cluster-based metal–organic frameworks

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Synthesis and functionality of transition metal-centered polyoxometalate-based crystalline framework materials

Cited by 5 publications

References 20 publications

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage

Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction

Enhancing catalytic aerobic oxidation performance of cyclohexaneviasize regulation of mixed-valence {V16} cluster-based metal–organic frameworks

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Enhancing catalytic aerobic oxidation performance of cyclohexaneviasize regulation of mixed-valence {V₁₆} cluster-based metal–organic frameworks