Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction

Metal-Oxo Cluster Catalysts for Photocatalytic Water Splitting and Carbon Dioxide Reduction

“…Recently, increasing attention has been paid to high-nuclear spin metal clusters because of their structural aesthetics [71][72][73], intriguing properties, and potential technological applications. These metal-oxo clusters are widely used in photocatalysis for water splitting and CO 2 reduction because of their unusual chemical activity and catalytic features [74].…”

Transformation of metal–organic frameworks with retained networks

“…[32][33][34][35][36][37][38][39] Hence, the materials derived from MOFs, with ordered porous structures, superior stability, adjustable active sites and tunable functions, represent a class of very promising candidates for applications in diverse fields, such as organo-/photo-/electro-catalysis, electrochemical energy storage and conversion, chemical sensing, gas adsorption and separation, wastewater treatment and biomedicine. [40][41][42][43][44][45][46][47][48][49][50] Among various transformation strategies for MOFs, considerable studies have been conducted on the fabrication of MOFderived metal nanomaterials, porous carbon materials and their composites by thermal treatment. 51 Thermal treatment of MOFs could transform the dynamic coordination networks into stable carbon matrices with enhanced endurance to acids, bases and chemical reagents.…”

Polyoxometalate-based metal–organic complexes and their derivatives as electrocatalysts for energy conversion in aqueous systems

“…This strategy is beneficial for building single-atom catalysts. Zhang's group 77 has successfully synthesized a kind of highly efficient oxygen reduction catalyst. The Co-containing POM [CoW 12 O 40 ] 6− was confined in the ZIF-8 MOF to act as a precursor.…”