“…Further, these glasses are considered very good materials for hosting lasing rare-earth ions since they provide a low phonon energy environment to minimize non-radiative losses. A number of recent investigations on mechanical, electrical and optical properties of various tellurite glasses mixed with different modifiers are available in the literature [1][2][3][4][5][6][7][8]. A considerable number of these studies on various physical properties have also been reported in the recent past from our laboratory on some TeO 2 -based glass systems [9][10][11][12][13][14].…”
“…Further, these glasses are considered very good materials for hosting lasing rare-earth ions since they provide a low phonon energy environment to minimize non-radiative losses. A number of recent investigations on mechanical, electrical and optical properties of various tellurite glasses mixed with different modifiers are available in the literature [1][2][3][4][5][6][7][8]. A considerable number of these studies on various physical properties have also been reported in the recent past from our laboratory on some TeO 2 -based glass systems [9][10][11][12][13][14].…”
“…a tunneling probability e À2aR ¼ 1 is possible. This has already been shown to be invalid for similar iron containing systems within the studied temperature interval [10][11][12][13][14][15]22,25,26]. In fact, the calculations carried out for the sub-system 16Na 2 O AE 10CaO AE (74 À y)SiO 2 AE yFe 2 O 3Àd show that the tunneling probability for this set of compositions is e À2aR $ 10 À9 -10 À6 , i.e.…”
Section: Resultsmentioning
confidence: 96%
“…The distances between the iron ions were calculated from the composition and the respective density, assuming a random distribution of the iron ions in the glass [21,22,25,26]. The values are summarized in Table 2, column 4.…”
Section: Resultsmentioning
confidence: 99%
“…The conductivity of phosphate, borate, vanadate and tellurite glasses and also of ternary silicate glasses containing transition metal ions has frequently been reported in the literature [10,[12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27]. Besides, the conductivity of glasses and glassy materials from the system PbO/SiO 2 / Fe 2 O 3 was studied [15].…”
“…Oxide glasses including transition metal ions were extensively studied due to their semiconducting properties [1][2][3][4][5][6]. The conduction in ternary iron oxide glasses was confirmed to be due to hopping conduction of polaron [7].…”
In this paper, we have analyzed the effects of iron ions intercalations on lead-tellurate glasses content up to 60mol%, the accommodation of the network with excess of oxygen can be
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