The effect of propylene glycol-water ratio on the final particles morphology of Eu doped Y 2 O 2 S red phosphor prepared by the complex homogeneous precipitation at 95°C and 160°C was examined. The synthesis method was based on hydrolysis of urea and precipitation of the hydroxide in the presence of a glycol under solvothremal conditions; the sulfurization of the powders was carried out at 1000°C in the N 2 -H 2 S gas. It was found that by changing the glycol concentration one may efficiently control the size of the particles in the range from 60 to 400 nm. The most homogeneous and non-agglomerated powders formed during precipitation at 160°C in the range of glycol-water mass ratios from 1:1 to 3:1. At the same time, the crystallinity determined from the XRD peaks broadening changes in a narrower range of 30-70 nm.