Synthesis and characterization of water-soluble zinc(II) Schiff-base complexes derived from amino acids and 3-formyl-4-hydroxybenzyl-triphenylphosphonium chloride
“…The proton of Schiff's base in the 1 H-NMR spectrum of PEI-al appeared at 8.36 ppm. [24][25][26] PVA-al has two additional signals at 7.7 and 6.3 ppm which are attributed to the presence of protons of the cyclic acetal form and multiples at 2.23 ppm related to glutaraldehyde moieties (CH 2 (4H)) and the singlets at 2.1 ppm attributed to an ethyl groups (CH 3 ) of PVA ( Fig. S1c †).…”
Section: Synthesis Of Aldehyde-modied Polymersmentioning
“…The proton of Schiff's base in the 1 H-NMR spectrum of PEI-al appeared at 8.36 ppm. [24][25][26] PVA-al has two additional signals at 7.7 and 6.3 ppm which are attributed to the presence of protons of the cyclic acetal form and multiples at 2.23 ppm related to glutaraldehyde moieties (CH 2 (4H)) and the singlets at 2.1 ppm attributed to an ethyl groups (CH 3 ) of PVA ( Fig. S1c †).…”
Section: Synthesis Of Aldehyde-modied Polymersmentioning
“…The coordination of azomethine nitrogen to metal ion was supported by upeld shiing of CH]N peak from 8.58 ppm in L1 to 8.30 ppm in the spectrum of complex 1. 23,24 In addition, the disappearance of the phenolic proton in the spectrum of complex 1 suggested the complexation of the ligand to metal ion via phenolate oxygen.…”
Section: Spectroscopic Measurements Of L1 and Complexes 1-4mentioning
Transition metal (Zn, Cu and Ni) derivatives of (2-[2-bromoethyliminomethyl]phenol), were found to inhibit topoisomerase I activity, induce DNA cleavage and bind to calf thymus DNA. The compounds are also cytotoxic and anti-invasive against PC3.
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