Synthesis and characterization of synthetic lubricants based on dibasic acid

Abstract

Synthetic esters have long been used in a variety of applications due to their excellent thermal stability, excellent cleanliness, natural lubricity, and polarity. In the present work, we aimed to prepare some synthetic base oils through preparation of different dibasic esters by esterification of dicarboxylic acids (adipic acid and azelaic acid) with different linear alcohols (hexanol, octanol, and decanol) and branched alcohol (2‐ethyl hexanol) at 120°C. The reaction yield ranges between 85% and 94%. Fourier‐transform infrared spectroscopy (FT‐IR) and proton nuclear magnetic resonance (1H‐NMR) spectroscopy were used to analyze the structures of the produced compounds. Using thermo gravimetric analysis (TGA), the heat stability of the produced esters was determined, and it was found that the prepared esters have high thermal stability. The degradation of the prepared esters takes place in the range between 300 and 600°C. The rheological behaviour of prepared esters shows Newtonian behaviours, which means that Newtonian fluids obey viscosity Newton's law. The viscosity is independent of the shear rate. The results showed that the lubricity properties, based on their pour point, flash point, and oxidation stability of the esters, were significantly affected by the linear and branched alcohols used. There is a slight increase in kinematic viscosity and viscosity index values with decreasing the internal chain length of the dibasic acid. The esters which were based on adipic acid such as C1 exhibited maximum values of VI: 187 compared to those which were based on azelaic acid such as F1 with VI: 182. Viscosity and viscosity index increases with increasing the number of carbon atoms of the used mono‐ol alcohols. Using branched alcohols gave almost the same viscosity results compared to using linear alcohol with the same number of carbons. Almost all prepared esters give pour point results ≤ −30°C.

Synthesis and biodegradation testing of some synthetic oils based on ester

“…Lubricating oil typically contains 80% hydrocarbon base oil and the rest is different additives. On the other hand, the green chemistry approach emphasizes the use of environmentally friendly materials- as possible- in different industries and applications 2 . This trend of replacing petroleum-based oils with more environmentally friendly insulating oils can also be seen in oil field transformer problems.…”

“…After simple filtration, the catalyst is easily recovered, and the reaction product solution is clean. Therefore, some considerations have been taken into account in esterification processes to the employment of heterogeneous catalysts 2 . On the other hand, bioremediation is a type of biodegradation in which microorganisms are used to free the environment from organic and inorganic xenobiotics via their enzymatic activity 9 .…”