2006
DOI: 10.1016/j.solidstatesciences.2006.02.025
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Synthesis and characterization of a new metal organic framework structure with a 2D porous system: (H2NEt2)2[Zn3(BDC)4]⋅3DEF

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Cited by 60 publications
(42 citation statements)
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“…[43,44] In the region of 1300-700 cm À1 , several bands are observed, and they are assigned to the out-of-plane vibrations of BDC. [44,45] After adsorption of ammonia, the spectra of MOF-5 and MOF-5/GO1 and MOF-5/GO2 do not change. However, a slight modification is observed around 1600 cm À1 for MOF-5/GO3.…”
Section: Resultsmentioning
confidence: 99%
“…[43,44] In the region of 1300-700 cm À1 , several bands are observed, and they are assigned to the out-of-plane vibrations of BDC. [44,45] After adsorption of ammonia, the spectra of MOF-5 and MOF-5/GO1 and MOF-5/GO2 do not change. However, a slight modification is observed around 1600 cm À1 for MOF-5/GO3.…”
Section: Resultsmentioning
confidence: 99%
“…In Figure 1a, the bands of 1400-1767 cm −1 are referred to as carboxylic functional groups [18]. The carboxyl groups from free aromatic carboxylic acid were observed at 1656 cm −1 [19] on the as-synthesized sample; however, the peak was removed after heat activation, due to solvent extraction and heat treatment. For the as-synthesized samples activated at 200 • C, the band of 1430-1533 cm −1 was observed, indicating the presence of aminocarboxylate compounds that were coordinated with zirconium metal center by -CO 2 asymmetrical stretching with the peaks at 1497 and 1564 cm −1 or -CO 2 symmetrical stretching with the peaks at 1385 and 1424 cm −1 [18,20,21].…”
Section: Breakthrough Experiments Of Co 2 Adsorptionmentioning
confidence: 99%
“…These compounds are mostly based on metal carboxylates, sulfonates, and phosphonates and are intensively investigated due to their potential applications as sorbents, ion exchangers, catalysts, or charge-storage materials. [2,3] Porous hybrid compounds based on metal carboxylates [4][5][6] and phosphonates [7][8][9][10] have attracted widespread interest in the past few years. We are interested in the use of organic ligands containing two or more different functional groups for the synthesis of functionalized porous hybrid compounds or bimetallic hybrid systems.…”
Section: Introductionmentioning
confidence: 99%