Synthesis and biological activity of gem-dichlorocyclopropyl ethers

Shostakovskii, S. M.; Mochalov, V. N.; Larionov, G. M.

doi:10.1007/bf00766631

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2015

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“…This is easily can be realized only in a case of cationic polymerization of vinylcyclopropyl ether (VCPE) and its derivatives [6]. In particular, the polymers containing macromolecules of gem-dichlorocyclopropyl groups in the side chain, prepared on the basis of vinylbutyl or vinyl-gemdichlorocyclopropyl ether in the presence of trifluoride boron etherate in hexane solution, possess bactericide properties [7]. In addition, it has been also detected the antiblastic action previously unknown for representatives of this class of compounds, which shows a perspectivity of further searches in series of new substances.…”

Section: Resultsmentioning

confidence: 99%

Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers

Shahnazarli¹,

Aliyeva²,

Guliyev³

2015

CBU J of Sci

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By cationic polymerization of substituted vinylcyclopropyl ethers a series of polyvinylcyclopropyl ethers has been prepared. By data of spectral analysis the structure of the prepared polymers has been established and it has been shown that the polymerization proceeds only with opening of double bond and conservation of cyclopropane ring. The influence of substituent of three-membered cycle on reactivity of the synthesized monomers has been estimated.

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Section: Resultsmentioning

confidence: 99%