By cationic polymerization of substituted vinylcyclopropyl ethers a series of polyvinylcyclopropyl ethers has been prepared. By data of spectral analysis the structure of the prepared polymers has been established and it has been shown that the polymerization proceeds only with opening of double bond and conservation of cyclopropane ring. The influence of substituent of three-membered cycle on reactivity of the synthesized monomers has been estimated.
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