“…Peaks at 1,558.54 and 1,401.05 cm -1 were assigned as ester groups (−COO - ), and a peak at 1,653.64 cm -1 indicated a carboxyl group (C=O). These findings supported the idea of Liu et al ( 2008 ) that these functional groups may improve soil aggregates with strong interactions between soil particles and BP molecules, thereby reducing soil loss. Our results were similar to their findings that the peaks of the ester and carboxyl groups were detected at 1,560 and 1,410 cm -1 , and at 1,680 and 1,450 cm -1 , respectively.…”
Section: Resultssupporting
confidence: 90%
“…Orts et al ( 2000 ) showed that the BP suspension made from microfibrils of cellulose, starch xanthate, chitosan, and acid-hydrolyzed cellulose microfibril, reduced soil sediment by an average of 80% compared to the CK. Application of the BP treatment should be practically used to not only reduce raindrop impacts such as soil-surface seal formation, soil detachment, and degradation of water quality, but also reproduce industrial wastes (Levin et al 1991 ; Orts et al 1999 2000 2007 ; Lee et al 2008 ; Liu et al 2008 ).…”
Section: Resultsmentioning
confidence: 99%
“…Characterization of the properties of each treatment were triplicated and shown in Table 1 . To synthesize BP, a total of 4-g lignin, 0.4-g corn starch, and 16-g acrylamide were completely homogenized with 100 mL of distilled water having an electrical conductivity (EC) of 4.17 × 10 -4 S m -1 and pH of 7.2, and then 12-mL acrylic acid was added (Liu et al 2008 ). The solution pH was adjusted to 7.5 by adding sodium hydroxide (NaOH) and was dissolved with 200 mL of distilled water.…”
Section: Methodsmentioning
confidence: 99%
“…More recently, a synthesized biopolymer (BP) was recognized as an alternative to conventional chemical-based tackifiers such as PAM. Natural and industrial by-products may be sources of BPs synthesis (Sojka et al 2007 ; Liu et al 2008 ). The BPs provide a cost advantage and an additional safety to environments by using natural and non-toxic materials such as lignin, starch, sugar, cellulose etc.…”
Soil erosion leads to environmental degradation and reduces soil productivity. The use of anionic polyacrylamide (PAM) and synthesized biopolymer (BP) using lignin, corn starch, acrylamide, and acrylic acid were tested to evaluate soil erosion, water quality, and growth of Chinese cabbage (Brassica campestris L.). Each treatment of PAM and BP was applied at 200 kg ha-1 to loamy sand soil and subjected to a slope of 36% with a 20 mm h-1 simulated rainfall. Application of BP decreased soil pH compared to the untreated check (CK); however, the soil pH was not altered with PAM. The decrease in pH might most likely be due to availability of anionic sites to be protonated on soils having pH >6 and soil buffering capacity. Both PAM and BP applications may not induce eutrophication with stable levels of total contents of N and P. With PAM and BP, the average values of suspended soil (SS) and turbidity were reduced by up to 96.0 and 99.9%, respectively, compared to CK. Reduction of SS can be attributed to increasing soil stability and shear strength by clay flocculation. There was no toxicity effects resulting from germination tests and the dry weight was increased by 17.7% (vs. CK) when PAM and BP were applied. These results are attributed to increases in water retention and plant-available water. The use of polymeric soil amendments is an environmentally friendly way to mitigate soil erosion and nonpoint source pollution.Electronic supplementary materialThe online version of this article (doi:10.1186/2193-1801-2-534) contains supplementary material, which is available to authorized users.
“…Peaks at 1,558.54 and 1,401.05 cm -1 were assigned as ester groups (−COO - ), and a peak at 1,653.64 cm -1 indicated a carboxyl group (C=O). These findings supported the idea of Liu et al ( 2008 ) that these functional groups may improve soil aggregates with strong interactions between soil particles and BP molecules, thereby reducing soil loss. Our results were similar to their findings that the peaks of the ester and carboxyl groups were detected at 1,560 and 1,410 cm -1 , and at 1,680 and 1,450 cm -1 , respectively.…”
Section: Resultssupporting
confidence: 90%
“…Orts et al ( 2000 ) showed that the BP suspension made from microfibrils of cellulose, starch xanthate, chitosan, and acid-hydrolyzed cellulose microfibril, reduced soil sediment by an average of 80% compared to the CK. Application of the BP treatment should be practically used to not only reduce raindrop impacts such as soil-surface seal formation, soil detachment, and degradation of water quality, but also reproduce industrial wastes (Levin et al 1991 ; Orts et al 1999 2000 2007 ; Lee et al 2008 ; Liu et al 2008 ).…”
Section: Resultsmentioning
confidence: 99%
“…Characterization of the properties of each treatment were triplicated and shown in Table 1 . To synthesize BP, a total of 4-g lignin, 0.4-g corn starch, and 16-g acrylamide were completely homogenized with 100 mL of distilled water having an electrical conductivity (EC) of 4.17 × 10 -4 S m -1 and pH of 7.2, and then 12-mL acrylic acid was added (Liu et al 2008 ). The solution pH was adjusted to 7.5 by adding sodium hydroxide (NaOH) and was dissolved with 200 mL of distilled water.…”
Section: Methodsmentioning
confidence: 99%
“…More recently, a synthesized biopolymer (BP) was recognized as an alternative to conventional chemical-based tackifiers such as PAM. Natural and industrial by-products may be sources of BPs synthesis (Sojka et al 2007 ; Liu et al 2008 ). The BPs provide a cost advantage and an additional safety to environments by using natural and non-toxic materials such as lignin, starch, sugar, cellulose etc.…”
Soil erosion leads to environmental degradation and reduces soil productivity. The use of anionic polyacrylamide (PAM) and synthesized biopolymer (BP) using lignin, corn starch, acrylamide, and acrylic acid were tested to evaluate soil erosion, water quality, and growth of Chinese cabbage (Brassica campestris L.). Each treatment of PAM and BP was applied at 200 kg ha-1 to loamy sand soil and subjected to a slope of 36% with a 20 mm h-1 simulated rainfall. Application of BP decreased soil pH compared to the untreated check (CK); however, the soil pH was not altered with PAM. The decrease in pH might most likely be due to availability of anionic sites to be protonated on soils having pH >6 and soil buffering capacity. Both PAM and BP applications may not induce eutrophication with stable levels of total contents of N and P. With PAM and BP, the average values of suspended soil (SS) and turbidity were reduced by up to 96.0 and 99.9%, respectively, compared to CK. Reduction of SS can be attributed to increasing soil stability and shear strength by clay flocculation. There was no toxicity effects resulting from germination tests and the dry weight was increased by 17.7% (vs. CK) when PAM and BP were applied. These results are attributed to increases in water retention and plant-available water. The use of polymeric soil amendments is an environmentally friendly way to mitigate soil erosion and nonpoint source pollution.Electronic supplementary materialThe online version of this article (doi:10.1186/2193-1801-2-534) contains supplementary material, which is available to authorized users.
“…The BP was synthesized by the method described by Liu et al . (). The BC contained 2.73% N and 67.0% C, PAM contained 16.2% N and 42.2% C, and BP contained 5.3% N and 28.4% C. Before the soil conditioner experiment, maize plants were labelled three times in a 14 CO 2 atmosphere to produce uniformly 14 C‐labelled plant residues, based on the method described by Gocke et al .…”
Summary
The efficacy of applying plant residues to agricultural soils as a carbon (C) source for microorganisms and C sequestration is dependent on soil physiochemical properties, which can be improved by aggregation using soil conditioners. However, no attempt has been made to assess the effects of soil conditioners such as biochar (BC), biopolymer (BP) or polyacrylamide (PAM) on plant residue decomposition. We assessed the effects of BC, synthesized BP and anionic PAM on the decomposition of 14C‐labelled maize residues and on their stabilization in aggregate fractions in sandy and sandy loam soils. Polyacrylamide and BP were applied at 400 kg ha−1 and BC was applied at 5000 kg ha−1, and the soils were incubated for 80 days at 22°C. The conditioners improved the physical and biological properties of both soils, as shown by a 24% increase in the 1–2 mm aggregates. Biochar and BP accelerated the decomposition of plant residues as indicated by 14CO2 efflux, and resulted in reduced stabilization of residues in both soils relative to that observed in the control and PAM treatments. The reduction in 14C incorporation and C stabilization in the BC‐ and BP‐treated soils was observed mainly in the < 0.25‐mm aggregates. This was confirmed by reduction of activity of hydrolytic enzymes (β‐cellobiosidase and β‐glucosidase). Decomposition of plant residues in sandy soil was more sensitive to BP and PAM application than that in sandy loam soil. Improved soil structure after applying BC and BP increased aeration and decreased the contact between plant residues and mineral soil particles and consequently accelerated plant residue decomposition and reduced C sequestration.
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