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Nightsoil and piggery wastes generally present high strength organics and nitrogen. This study evaluated the nitrogen removal characteristics with the existing and modified nightsoil and piggery waste treatment plants. The existing conventional plants showed 20 to 40% nitrogen removal, but the modification with SBR or MLE process could remove effectively both nitrogen and organics with the minimum COD/TN and alkalinity/TN ratios of 6 and 3.6, respectively. Nitrite nitrification and denitrification rates obtainable at higher nitrogen loads were faster than the rates of nitrate nitrification and denitrification resulting in less reactor volume requirement. However, the higher nitrogen loads increased the organic loads resulting in the reactor temperature inhibiting nitrification. Thus, a combined treatment with anaerobic digestion with the adjustment of influent bypass rates was proposed to reduce the reactor temperature and the external carbon requirement. The biological treatment could discharge about 1,100 mg/L soluble COD and 50 mg/L soluble nitrogen, respectively.

Photocatalytic degradation of reactive dye, Red 120, was carried out on TiO2 particles as photocatalyst under UV irradiation. In this experiment, comparison on the removal of reactive dye by photolysis using UV light alone, photocatalyst adsorption using TiO2 alone and photocatalysis using UV light with photocatalysts as well as the effect of experimental parameters such as the number of column employed, intensity of the light, pH and TiO2 dosage affecting the reaction efficiency of photocatalytic degradation of reactive dye in circular type reactor was examined. The results of this indicate that with both UV light illumination and TiO2 present, reactive dye was more effectively eliminated than with either UV or TiO2 alone. Photocatalytic degradation of reactive dye increased linearly with increasing UV light intensity. However, over 18 mW cm(-2) of UV light intensity, the efficiency reached a plateau. The photocatalytic degradation rate was greater in acid media than in alkaline media. Photocatalytic removal efficiency of reactive dye increased with increasing TiO2 dosage. However, over 1.5 g L(-1) of TiO2 dosage, the efficiency reached a plateau.

Litter characterization is an integrated part of the Caltrans First Flush Characterization Study. These data will provide a basis to develop potential treatment technologies and best management practices to control pollutants in runoff from freeways. During monitoring periods in Southern California areas, the first flush phenomenon was evaluated and the impacts of various parameters such as rain intensity, drainage area, peak flow rate, and antecedent dry period on litter volume and loading rates were evaluated. First flush phenomenon was generally observed for litter concentrations, but was not apparent with litter mass loading rates. Total captured gross pollutants, defined as larger than 0.5 cm, was 90% vegetation with only 10% being litter. The normalized cumulative litter loadings were determined from 1.25 to 13.39 kg/ha for dry litter weight and 0.40 to 8.99 kg/ha for dry biodegradable litter weight. The portions of biodegradable litter to non-biodegradable litter were roughly the same across the entire event. Event mean concentrations were ranged 0.0021 to 0.259 g/L for wet gross pollutants, 0.0001 to 0.027 g/L for wet litters and 0.00007 to 0.018 g/L for dry litters. The mass emission rates should be useful to estimate total litter production for developing total maximum daily loads.

Specific fecal DNA markers were investigated for major pollution sources, cow, human, and pig, and occurrence of the identified markers was analyzed in river waters using Terminal Restriction Fragment Length Polymorphism (T-RFLP) techniques and sequencing of 16S rDNA of Bacteroides-Prevotella. The unique and specific DNA markers for cow and human were identified as a 222 bp and 60 bp peak in HaeIII T-RFLP profiles, respectively, and the pig-specific marker was not identified but the unique T-RFLP profile of pig could be used as a substitution. Human-specific marker was detected in most of the river waters tested (92.1%) and T-RFLP profiles of river waters were shown to be similar to those of human feces. Cluster analysis of T-RFLP data showed that the fecal sources were multiple (human plus cow and human plus dairy cow) in most of the river waters. The phylogenetic analysis for the clones recovered from the fecal and water samples showed that the clones from cow formed a discreet cluster from those of other sources. The other clones from human, pig, and river water formed two groups all together. The results of this study could be used to identify and control the fecal pollution source in the bodies of water in Korea.

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Experimental investigations were performed to determine the possibility of simultaneous biological nitrogen and phosphorus removal during various biofilm processes in conjunction with biofilm characterisation, especially extracellular polymeric substance (EPS). Since biologial nitrogen removal requires an alternating exposure of anaerobic-anoxic-oxic conditions in the bulk liquid that surrounds the biofilm growth media, a sequencing batch reactor (SBR)-type operation was used. Various materials including expanded clay, polystyrene, polyurethane, and acrylic materials were used as the biofilm growth support medium. Simultaneous nitrogen and phosphorus removal was possible with SBR, but it was postulated that nutrient removal efficiencies varied with film thickness. Thinner biofilm promoted nitrification and phosphorus removal, but thicker biofilm enhanced denitrification and reduced phosphorus removal. EPS contents were similar regardless of support media types or biofilm configuration, but EPS contents gradually increased as the film growth continued after backwashing. EPS contents were increased with increased nitrogen removal, but it was difficult to define its relation with phosphorus removal. In addition, suspended solids removal was correlated well with the EPS content in the biofilms.