Syntheses, displacement behavior, hetero-atom carbene, and crystal structures of platinum complexes containing the N,N-dimethylthiocarbamoyl, Me2NCS, ligand: Structures of [Pt(PPh3)(Cl)]2(μ,η2-SCNMe2)2, [Pt(PPh3)(η2-dppa){η1-C(S)NMe2}][Cl], and [Pt(PPh3)2{η1-C(SEt)(NMe2)}(η2-S2CO)]

Synthesis and Crystal Structures of the Molybdenum(II) Complexes with the N,N‐dimethylthiocarbamoyl Containing Ligand: Crystal Structures of [Mo(CO)2(η2‐S2COEt)(η2‐SCNMe2)(PPh3)] and [Mo(CO)2(η2‐S2CNC4H8)(η2‐SCNMe2)(PPh3)]

“…5 These complexes have been prepared from the reaction of metal carbonylates with N,N-dimethylthiocarbamoyl chloride, Me 2 NC(=S)Cl, via nucleophilic displacement of chloride, 6 nucleophilic attack by an amine on the electrophilic thiocarbonyl complex, 7 electrophilic attack at a coordinated isothiocyanate, 8 reaction of hydrosulfide with haloaminocarbene 9 or isonitrile 10 ligands, cleavage of the dithiocarbamate ligand, 11 or C-H activation of thioformamides. 12 Oxidative addition 13 of both chloride and N,Ndimethylthiocarbamoyl ligands to the metal complex are most generally used and relevant to the work described herein.…”